Carbamic acid, (2,2-dimethoxyethyl)-, 1,1-dimethylethyl ester (9CI)

Base Information

• Chemical Name: Carbamic acid, (2,2-dimethoxyethyl)-, 1,1-dimethylethyl ester (9CI)
• CAS No.: 127119-09-9
• Molecular Formula: C₉H₁₉NO₄
• Molecular Weight: 205.254
• Mol file: 127119-09-9.mol

Synonyms:Carbamicacid, (2,2-dimethoxyethyl)-, 1,1-dimethylethyl ester (9CI)

Chemical Property of Carbamic acid, (2,2-dimethoxyethyl)-, 1,1-dimethylethyl ester (9CI)

Chemical Property:

• Boiling Point: 274.5±30.0 °C(Predicted)
• PKA: 12.63±0.46(Predicted)
• PSA: 56.79000
• Density: 1.013±0.06 g/cm3(Predicted)
• LogP: 1.52090

Purity/Quality:

≥99.0% ^*data from raw suppliers

tert-Butyl(2,2-Dimethoxyethyl)carbamate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Carbamic acid, (2,2-dimethoxyethyl)-, 1,1-dimethylethyl ester (9CI)

There total 1 articles about Carbamic acid, (2,2-dimethoxyethyl)-, 1,1-dimethylethyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

di-tert-butyl dicarbonate (24424-99-5) + 2,2-dimethoxyethylamine (22483-09-6) → (2,2-dimethoxy-ethyl)-carbamic acid tert-butyl ester (127119-09-9)

Guidance literature:

With indium(III) bromide; at 30 - 35 ℃; for 0.0833333h;

DOI:10.1055/s-2006-942492

upstream raw materials:

di-tert-butyl dicarbonate

2,2-dimethoxyethylamine

Refernces

• 1、 Pise, Ashok S.,Ingale, Ajit P.,Dalvi, Navnath R.. "Ultrasound promoted environmentally benign, highly efficient, and chemoselective N-tert-butyloxycarbonylation of amines by reusable sulfated polyborate". supporting information. p. 3768 - 3780. Retrieved 2021/10/26.
• 2、 Sarkar, Anirban,Roy, Sudipta Raha,Parikh, Naisargee,Chakraborti, Asit K.. "Nonsolvent application of ionic liquids: Organo-catalysis by 1-alkyl-3-methylimidazolium cation based room-temperature ionic liquids for chemoselective N-tert-butyloxycarbonylation of amines and the influence of the C-2 hydrogen on catalytic efficiency". experimental part. p. 7132 - 7140. Retrieved 2011/10/08.