Carbamic acid, (2-hydroxy-3-butenyl)-, 1,1-dimethylethyl ester (9CI)

Base Information

Chemical Name:Carbamic acid, (2-hydroxy-3-butenyl)-, 1,1-dimethylethyl ester (9CI)
CAS No.:134676-36-1
Molecular Formula:C₉H₁₇NO₃
Molecular Weight:187.239
Hs Code.:
Mol file:134676-36-1.mol

Synonyms:Carbamic acid, (2-hydroxy-3-butenyl)-, 1,1-dimethylethyl ester (9CI)

Suppliers and Price of Carbamic acid, (2-hydroxy-3-butenyl)-, 1,1-dimethylethyl ester (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Carbamic acid, (2-hydroxy-3-butenyl)-, 1,1-dimethylethyl ester (9CI)

Chemical Property:

PSA：0.00000
LogP:0.00000

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Carbamic acid, (2-hydroxy-3-butenyl)-, 1,1-dimethylethyl ester (9CI)

There total 1 articles about Carbamic acid, (2-hydroxy-3-butenyl)-, 1,1-dimethylethyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 31954-27-5
N-(tert-butoxycarbonyl)glycine methyl ester

: 134676-36-1,1267551-72-3
(2-Hydroxy-but-3-enyl)-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: DIBAL-H / toluene / -78 °C

2: tetrahydrofuran

With diisobutylaluminium hydride; In tetrahydrofuran; toluene;
DOI:10.1016/S0040-4039(98)00534-6

Reference yield: 63.0%

: 201230-82-2
carbon monoxide

: 696-62-8
para-iodoanisole

: 134676-36-1,1267551-72-3
(2-Hydroxy-but-3-enyl)-carbamic acid tert-butyl ester

: C₁₇H₂₃NO₅

Guidance literature:: With bis(η3-allyl-μ-chloropalladium(II)); N-ethyl-N,N-diisopropylamine; XPhos; In 1,4-dioxane; at 100 ℃; for 18h;
DOI:10.1021/acscatal.6b00733

Reference yield:

: 134676-36-1,1267551-72-3
(2-Hydroxy-but-3-enyl)-carbamic acid tert-butyl ester

: 69974-30-7
3-phenyl-5-vinyl-oxazolidin-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydride / tetrahydrofuran / 17 h / -78 - 20 °C / Inert atmosphere

2: copper(I) oxide; sodium t-butanolate / 1-methyl-pyrrolidin-2-one / 24 h / 100 °C

With copper(I) oxide; sodium hydride; sodium t-butanolate; In tetrahydrofuran; 1-methyl-pyrrolidin-2-one;
DOI:10.1021/jacs.9b13026