Methyl [2-(4-bromophenyl)ethenyl]carbamate

Base Information

Chemical Name:Methyl [2-(4-bromophenyl)ethenyl]carbamate
CAS No.:135879-71-9
Molecular Formula:C10H10BrNO2
Molecular Weight:256.1
Hs Code.:
DSSTox Substance ID:DTXSID70700949
Mol file:135879-71-9.mol

Synonyms:Methyl [2-(4-bromophenyl)ethenyl]carbamate;135879-71-9;METHYL N-[2-(4-BROMOPHENYL)ETHENYL]CARBAMATE;DTXSID70700949

Suppliers and Price of Methyl [2-(4-bromophenyl)ethenyl]carbamate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of Methyl [2-(4-bromophenyl)ethenyl]carbamate

Chemical Property:

Vapor Pressure:0.000118mmHg at 25°C
Refractive Index:1.597
Boiling Point:335.6°Cat760mmHg
Flash Point:156.8°C
PSA：38.33000
Density:1.46g/cm³
LogP:3.16670
XLogP3:2.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:254.98949
Heavy Atom Count:14
Complexity:210

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(=O)NC=CC1=CC=C(C=C1)Br

Technology Process of Methyl [2-(4-bromophenyl)ethenyl]carbamate

There total 2 articles about Methyl [2-(4-bromophenyl)ethenyl]carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 67-56-1
methanol

: 130973-06-7
(E)-3-(4-bromophenyl)acrylamide

: 135879-71-9
[(E)-2-(4-Bromo-phenyl)-vinyl]-carbamic acid methyl ester

Guidance literature:: With sodium hypochlorite; at 70 ℃; for 0.0833333h;
DOI:10.1055/s-1991-26512

Reference yield:

: 589-87-7
1,4-bromoiodobenzene

: 135879-71-9
[(E)-2-(4-Bromo-phenyl)-vinyl]-carbamic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / NaOAc / <*>-p-C₆H₄-(1,10-phenanthroline)-palladium⁽⁰⁾ / dimethylformamide; H₂O / 11 h / 100 °C

2: 72 percent / NaOCl / 0.08 h / 70 °C

With sodium hypochlorite; sodium acetate; <*>-p-C6H4-(1,10-phenanthroline)-palladium(0); In water; N,N-dimethyl-formamide;
DOI:10.1055/s-1991-26512