myo-Inositol, 1-O-(4-methoxyphenyl)methyl-2,4,5,6-tetrakis-O-(phenylmethyl)-

Base Information

• Chemical Name: myo-Inositol, 1-O-(4-methoxyphenyl)methyl-2,4,5,6-tetrakis-O-(phenylmethyl)-
• CAS No.: 140887-09-8
• Molecular Formula: C₄₂H₄₄O₇
• Molecular Weight: 660.807
• Mol file: 140887-09-8.mol

Synonyms:DL-myo-Inositol,1-O-[(4-methoxyphenyl)methyl]-2,4,5,6-tetrakis-O-(phenylmethyl)-

Chemical Property of myo-Inositol, 1-O-(4-methoxyphenyl)methyl-2,4,5,6-tetrakis-O-(phenylmethyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of myo-Inositol, 1-O-(4-methoxyphenyl)methyl-2,4,5,6-tetrakis-O-(phenylmethyl)-

There total 28 articles about myo-Inositol, 1-O-(4-methoxyphenyl)methyl-2,4,5,6-tetrakis-O-(phenylmethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

benzyl bromide (100-39-0) + (+/-)-2,4,5-Tri-O-benzyl-1-O-p-methoxybenzyl-myo-inositol (136091-46-8,141040-54-2,145843-77-2,145843-81-8,146611-39-4) → (1R,2R,3S,4R,5R,6R)-2,3,4,6-Tetrakis-benzyloxy-5-(4-methoxy-benzyloxy)-cyclohexanol (140887-09-8,141040-56-4) + (+/-)-2,3,5,6-Tetra-O-benzyl-1-O-p-methoxybenzyl-myo-inositol (134039-21-7,134107-72-5,134107-73-6,141040-52-0)

Guidance literature:

With tetrabutylammomium bromide; di(n-butyl)tin oxide; In acetonitrile; for 20h; Yields of byproduct given; Heating;

DOI:10.1016/S0008-6215(00)90497-X

Reference yield: 56.0%

2,4,5,6-tetra-O-benzyl-DL-myo-inositol (141040-63-3) + p-methoxybenzyl chloride (824-94-2) → (1R,2R,3S,4R,5R,6R)-2,3,4,6-Tetrakis-benzyloxy-5-(4-methoxy-benzyloxy)-cyclohexanol (140887-09-8,141040-56-4)

Guidance literature:

With sodium hydride; In tetrahydrofuran; Ambient temperature;

Reference yield:

1-Methoxy-4-{(1S,2R,3R,4S,5R,6S)-2,3,4,6-tetrakis-benzyloxy-5-[((E)-propenyl)oxy]-cyclohexyloxymethyl}-benzene → (1R,2R,3S,4R,5R,6R)-2,3,4,6-Tetrakis-benzyloxy-5-(4-methoxy-benzyloxy)-cyclohexanol (140887-09-8,141040-56-4)

Guidance literature:

With hydrogenchloride; acetone; In methanol; at 50 ℃; for 0.5h;

DOI:10.1016/S0008-6215(96)00211-X

upstream raw materials:

benzyl bromide

(+/-)-2,4,5-Tri-O-benzyl-1-O-p-methoxybenzyl-myo-inositol

2,4,5,6-tetra-O-benzyl-DL-myo-inositol

p-methoxybenzyl chloride

Downstream raw materials:

(-)-2,4,5,6-tetra-O-benzyl-myo-inositol 3-(dibenzyl phosphate)

1D-2,4,5,6-tetra-O-benzyl-3-O-(4'-methoxybenzyl)-myo-inositol

(+)-2,4,5,6-tetra-O-benzyl-1-O-(p-methoxybenzyl)-myo-inositol

(-)-2,4,5,6-tetra-O-benzyl-1-O-(p-methoxybenzyl)-myo-inositol 3-(dibenzyl phosphate)