Octanoic acid, 4-methyl-, ethyl ester, (.+/-.)-

Base Information

• Chemical Name: Octanoic acid, 4-methyl-, ethyl ester, (.+/-.)-
• CAS No.: 54831-51-5
• Molecular Weight: 0
• Mol file: 54831-51-5.mol

Synonyms:Octanoic acid, 4-methyl-, ethyl ester, (.+/-.)-

Chemical Property of Octanoic acid, 4-methyl-, ethyl ester, (.+/-.)-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Octanoic acid, 4-methyl-, ethyl ester, (.+/-.)-

There total 31 articles about Octanoic acid, 4-methyl-, ethyl ester, (.+/-.)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.9%

diethyl 2-methylhexylmalonate (63037-60-5) → (+/-)-Ethyl 4-methyloctanoate (56196-53-3,54831-51-5)

Guidance literature:

With water; sodium chloride; In N,N-dimethyl acetamide; at 139 ℃; for 13.5h;

Reference yield: 92.0%

2-iodohexane (18589-27-0) + ethyl acrylate (140-88-5,9003-32-1) → (+/-)-Ethyl 4-methyloctanoate (56196-53-3,54831-51-5)

Guidance literature:

With borohydride exchange resin; nickel diacetate; In methanol; at 20 ℃; for 1h;

DOI:10.1016/0040-4039(96)00510-2

Reference yield: 79.8%

1-chloro-2-methylhexane + diethyl malonate (105-53-3) → (+/-)-Ethyl 4-methyloctanoate (56196-53-3,54831-51-5)

Guidance literature:

1-chloro-2-methylhexane; diethyl malonate; With potassium carbonate; sodium iodide; In N,N-dimethyl acetamide; at 130 ℃; for 9h;

With water; In N,N-dimethyl acetamide; at 116 ℃; for 12h;

upstream raw materials:

(4R)-4-Methyloctanoic acid

ethanol

rac-4-methyloctanoic acid

(S)-3,7-dimethyl-6-octen-1-ol

Downstream raw materials:

(-)(R)-2.5-dimethyl-nonane