Chlorozinc(1+);1-methanidyl-3-(trifluoromethyl)benzene

Base Information

Chemical Name:Chlorozinc(1+);1-methanidyl-3-(trifluoromethyl)benzene
CAS No.:480438-42-4
Molecular Formula:C8H6ClF3Zn
Molecular Weight:259.974
Hs Code.:
DSSTox Substance ID:DTXSID80459890
Mol file:480438-42-4.mol

Synonyms:chlorozinc(1+);1-methanidyl-3-(trifluoromethyl)benzene;DTXSID80459890

Suppliers and Price of Chlorozinc(1+);1-methanidyl-3-(trifluoromethyl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
3-(Trifluoromethyl)benzylzinc chloride solution 0.5?M in THF
50ml
$ 350.00

Rieke Metals
3-Trifluoromethylbenzylzincchloride
100mL
$ 402.00

American Custom Chemicals Corporation
3-TRIFLUOROMETHYLBENZYLZINC CHLORIDE 95.00%
1L
$ 8431.50

American Custom Chemicals Corporation
3-TRIFLUOROMETHYLBENZYLZINC CHLORIDE 95.00%
500ML
$ 5313.00

American Custom Chemicals Corporation
3-TRIFLUOROMETHYLBENZYLZINC CHLORIDE 95.00%
100ML
$ 2702.70

Total 9 raw suppliers

Chemical Property of Chlorozinc(1+);1-methanidyl-3-(trifluoromethyl)benzene

Chemical Property:

Vapor Pressure:12.4mmHg at 25°C
Refractive Index: ">
Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：0.00000
Density:g/cm³
LogP:3.70810
Storage Temp.:2-8°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:257.940154
Heavy Atom Count:13
Complexity:130

Purity/Quality:

99% ^*data from raw suppliers

3-(Trifluoromethyl)benzylzinc chloride solution 0.5?M in THF ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F,Xi,Xn
Statements: 11-19-36/37-40
Safety Statements: 16-29-33-36/37-26

MSDS Files:

Useful:

Canonical SMILES:[CH2-]C1=CC(=CC=C1)C(F)(F)F.Cl[Zn+]

Technology Process of Chlorozinc(1+);1-methanidyl-3-(trifluoromethyl)benzene

There total 1 articles about Chlorozinc(1+);1-methanidyl-3-(trifluoromethyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 705-29-3
3-Trifluoromethylbenzyl chloride

: 7646-85-7,24359-56-6
zinc(II) chloride

: 480438-42-4
(3-(trifluoromethyl) benzyl)zinc(II) chloride

Guidance literature:: zinc(II) chloride; With lithium chloride; at 320 - 450 ℃; for 0.166667h; Inert atmosphere; Schlenk technique;

3-Trifluoromethylbenzyl chloride; With magnesium; In tetrahydrofuran; at 20 ℃; for 1.5h; Inert atmosphere; Schlenk technique;
DOI:10.1039/c5cc10272c

Reference yield: 92.0%

: 58481-11-1
methyl 2-chloroisonicotinate

: 480438-42-4
(3-(trifluoromethyl) benzyl)zinc(II) chloride

: 1251844-80-0
Methyl 2-(3-(trifluoromethyl)benzyl)isonicotinate

Guidance literature:: tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 60 ℃; Inert atmosphere;

Reference yield: 92.0%

: 122539-74-6
2-trifluoromethanesulfonyloxy-cyclopent-1-enecarboxylic acid ethyl ester

: 480438-42-4
(3-(trifluoromethyl) benzyl)zinc(II) chloride

: ethyl 2-(3-(trifluoromethyl)benzyl)cyclopent-1-enecarboxylate

Guidance literature:: With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; In tetrahydrofuran; at 20 ℃; Inert atmosphere;