(2-Methylpyridin-1-ium-1-yl)azanide

Base Information

• Chemical Name: (2-Methylpyridin-1-ium-1-yl)azanide
• CAS No.: 51135-75-2
• Molecular Formula: C₆H₈N₂
• Molecular Weight: 108.143
• DSSTox Substance ID: DTXSID401272117
• Mol file: 51135-75-2.mol

Synonyms:NCIOpen2_002053;51135-75-2;DTXSID401272117;Pyridinium, 1-amino-2-methyl-, inner salt;Pyridinium, 1-amino-2-methyl-, hydroxide, inner salt

Chemical Property of (2-Methylpyridin-1-ium-1-yl)azanide

Chemical Property:

• PSA: 32.24000
• LogP: 1.78780
• XLogP3: 1.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 108.068748264
• Heavy Atom Count: 8
• Complexity: 72.9

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=CC=[N+]1[NH-]

Technology Process of (2-Methylpyridin-1-ium-1-yl)azanide

There total 1 articles about (2-Methylpyridin-1-ium-1-yl)azanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

α-picoline (109-06-8) → 2-methylpyridine N-imine (51135-75-2)

Guidance literature:

With potassium carbonate; sodium hydroxylamine-O-sulfonate; Multistep reaction; 1.) water, room temperature, 2.) ethanol, 0.5 h;

DOI:10.1248/cpb.38.2662

Reference yield:

benzoyl chloride (98-88-4) + 2-methylpyridine N-imine (51135-75-2) → 2-methyl-N-(benzoylimino)pyridinium ylide (17408-47-8)

Guidance literature:

With sodium hydroxide; at 25 ℃; for 12h; Yield given;

DOI:10.1021/jm00384a018

Reference yield:

2-methylpyridine N-imine (51135-75-2) → N-(2-Methyl-3,6-dihydro-2H-pyridin-1-yl)-benzamide (104642-65-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 10percent aq. NaOH / 12 h / 25 °C

2: 45 percent / NaBH₄ / ethanol / 5 h / 0 °C

With sodium hydroxide; sodium tetrahydroborate; In ethanol;

DOI:10.1021/jm00384a018

upstream raw materials:

α-picoline

Downstream raw materials:

2-methyl-N-(benzoylimino)pyridinium ylide

N-(2-Methyl-3,6-dihydro-2H-pyridin-1-yl)-benzamide

2-methyl-N-(3,5-trifluoromethylbenzoyl)iminopyridinium ylide

(4-methoxybenzoyl)(2-methylpyridin-1-ium-1-yl)amide