Diphenic acid diallyl

Base Information

• Chemical Name: Diphenic acid diallyl
• CAS No.: 51256-00-9
• Molecular Formula: C20H18O4
• Molecular Weight: 322.361
• Mol file: 51256-00-9.mol

Synonyms:Diphenic acid diallyl

Chemical Property of Diphenic acid diallyl

Chemical Property:

• PSA: 52.60000
• LogP: 4.03920

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Diphenic acid diallyl

There total 3 articles about Diphenic acid diallyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

diphenic acid (863305-32-2) + allyl bromide (106-95-6) → diprop-2-en-1-yl biphenyl-2,2'-dicarboxylate (51256-00-9)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 6h; Inert atmosphere;

DOI:10.1002/ejoc.201301239

Reference yield:

2,2'-biphenyldicarboxylic acid dichloride (7535-15-1) + allyl alcohol (107-18-6) → diprop-2-en-1-yl biphenyl-2,2'-dicarboxylate (51256-00-9)

Guidance literature:

at 105 ℃; for 6h; Temperature;

Reference yield:

→ diprop-2-en-1-yl biphenyl-2,2'-dicarboxylate (51256-00-9)

Guidance literature:

upstream raw materials:

diphenic acid

allyl bromide

2,2'-biphenyldicarboxylic acid dichloride

allyl alcohol

Downstream raw materials:

bisbenzocyclobutene

cyclopenta[ a ]indene

acenaphthylene

Refernces

• 1、 Muthusamy, Sengodagounder,Azhagan, Datshanamoorthy. "Titanium isopropoxide promoted tandem self-cross and ring-closing metathesis approach for the synthesis of macrotetralides". . p. 363 - 370. Retrieved 2014/01/23.
• 2、 Bapat, Jayant B.,Brown, Roger F.C.,Bulmer, Glenn H.,Childs, Trevor,Coulston, Karen J.,Eastwood, Frank W.,Taylor, Dennis K.. "Formation of cyclopent[a]indene and acenaphthylene from allyl esters of biphenyl mono- and di-carboxylic acids and from biphenyl dicarboxylic anhydrides on flash vacuum pyrolysis at 1000-1100°C". . p. 1159 - 1182. Retrieved 2007/10/03.