5,10,15,20-Tetrakis(2,4,6-trimethylphenyl)-21H,23H-porphine

Base Information

• Chemical Name: 5,10,15,20-Tetrakis(2,4,6-trimethylphenyl)-21H,23H-porphine
• CAS No.: 56396-12-4
• Molecular Formula: C56H54N4
• Molecular Weight: 783.072
• Mol file: 56396-12-4.mol

Synonyms:meso-Tetra(2,4,6-trimethylphenyl)porphine;

Chemical Property of 5,10,15,20-Tetrakis(2,4,6-trimethylphenyl)-21H,23H-porphine

Chemical Property:

• Refractive Index: 1.639
• PSA: 56.30000
• Density: 1.142g/cm³
• LogP: 10.56700
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

98% ^*data from raw suppliers

meso-Tetra(2,4,6-trimethylphenyl)porphine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: meso-Tetra(2,4,6-trimethylphenyl)porphine is a porphyrin that can be used in the matrix for MALDI-TOFMS experiments.

Technology Process of 5,10,15,20-Tetrakis(2,4,6-trimethylphenyl)-21H,23H-porphine

There total 20 articles about 5,10,15,20-Tetrakis(2,4,6-trimethylphenyl)-21H,23H-porphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

pyrrole (109-97-7,30604-81-0) + mesytaldehyde (487-68-3) → 5,10,15,20-tetramesitylporphyrin (56396-12-4)

Guidance literature:

With titanium tetrachloride; In dichloromethane; for 1h; Ambient temperature; other reagents: VOCl₃, VO(OEt)Cl₂, VO(OiPr)Cl₂, Mn(OAc)3;

Reference yield: 28.0%

pyrrole (109-97-7,30604-81-0) + mesytaldehyde (487-68-3) + 4-formyl-5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene (158399-19-0) → 5-[2,7-di-tert-butyl-5-methoxycarbonyl-9,9-dimethylxanthen-4-yl]-10,15,20-tris(2,4,6-trimethylphenyl)porphyrin + 5,10,15,20-tetramesitylporphyrin (56396-12-4)

Guidance literature:

pyrrole; mesytaldehyde; 4-formyl-5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene; With boron trifluoride diethyl etherate; In chloroform; for 1h; Darkness; Inert atmosphere;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In chloroform; for 1h;

DOI:10.1021/ol902947h

Reference yield: 28.0%

→ 5-[2,7-di-tert-butyl-5-methoxycarbonyl-9,9-dimethylxanthen-4-yl]-10,15,20-tris(2,4,6-trimethylphenyl)porphyrin + 5,10,15,20-tetramesitylporphyrin (56396-12-4)

Guidance literature:

upstream raw materials:

pyrrole

mesytaldehyde

C₅₆H₅₂N₄O^(2-)*C₇H₄ClO₂^(1-)*Fe⁽³⁺⁾

4-[(trimethylsilyl)ethynyl]bezaldehyde

Downstream raw materials:

chloro(tetramesitylporphinato)thallium(III)

(carbonyl)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II)

5,10,15,20-tetra(2',4',6'-trimethylphenyl)porphyrinatoiron(III) chloride

(tetrakis(2,4,6-trimethylphenyl)porphyrinato)zinc(II)