ARSENIC TRI-N-BUTYL

Base Information

• Chemical Name: ARSENIC TRI-N-BUTYL
• CAS No.: 5852-58-4
• Molecular Formula: C12H27As
• Molecular Weight: 246.26
• Mol file: 5852-58-4.mol

Synonyms:TRI-N-BUTYL ARSINE;ARSENIC TRI-N-BUTYL

Chemical Property of ARSENIC TRI-N-BUTYL

Chemical Property:

• Vapor Pressure: 0.0162mmHg at 25°C
• Boiling Point: 264.1°C at 760 mmHg
• Flash Point: 107.8°C
• PSA: 0.00000
• Density: 0.9931 g/cm3(Temp: 21 °C)
• LogP: 4.88150

Purity/Quality:

99% ^*data from raw suppliers

ARSENIC TRI-N-BUTYL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ARSENIC TRI-N-BUTYL

There total 10 articles about ARSENIC TRI-N-BUTYL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C6H5CCo3(CO)8As(C4H9-n)3 → C6H5CCo3(CO)9 + tri-n-butylarsine (5852-58-4)

Guidance literature:

With carbon monoxide;

DOI:10.1016/S0022-328X(00)81102-X

Reference yield:

1-bromo-butane (109-65-9) → tri-n-butylarsine (5852-58-4)

Guidance literature:

1-bromo-butane; With magnesium; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

With arsenic triiodide; In tetrahydrofuran; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.21577/0103-5053.20200242

Reference yield:

n-butyl magnesium bromide (693-03-8) → tri-n-butylarsine (5852-58-4)

Guidance literature:

With diethyl ether; arsenic trichloride;

DOI:10.1021/ja01871a514

upstream raw materials:

n-butyl magnesium bromide

{Pd(As(C₄H₉)3)2Cl₂}

n-butyllithium

1-bromo-butane

Downstream raw materials:

gersdorffite

Refernces

• 1、 Brice,Penfold,Robinson, Ward T.,Taylor, Susan R.. "Structural studies of derivatives of methinyltricobalt enneacarbonyls. I. The crystal structure of CH3CCo3(CO)8P(C6H5) 3". . p. 362 - 367. Retrieved 2008/10/08.