TETRA-N-BUTYLAMMONIUM DIBROMOAURATE

Base Information

• Chemical Name: TETRA-N-BUTYLAMMONIUM DIBROMOAURATE
• CAS No.: 50481-01-1
• Molecular Formula: C16H36AuBr2N
• Molecular Weight: 599.243
• Hs Code.: 2923900090
• Mol file: 50481-01-1.mol

Synonyms:TETRA-N-BUTYLAMMONIUM DIBROMOAURATE;Tetrabutylammoniumdibromoaurate

Chemical Property of TETRA-N-BUTYLAMMONIUM DIBROMOAURATE

Chemical Property:

• PSA: 0.00000
• LogP: 6.69230

Purity/Quality:

99% ^*data from raw suppliers

Tetrabutylammonium Dibromoaurate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TETRA-N-BUTYLAMMONIUM DIBROMOAURATE

There total 1 articles about TETRA-N-BUTYLAMMONIUM DIBROMOAURATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

tetrabutylammonium tetrabromoaurate(III) (17769-65-2) → tetra-n-butylammonium dibromoaurate(I) (50481-01-1)

Guidance literature:

In ethanol; acetone; at 70 ℃; for 2h;

DOI:10.1002/anie.201803965

Reference yield: 87.0%

tetra-n-butylammonium dibromoaurate(I) (50481-01-1) + tetra-(n-butyl)ammonium iodide (311-28-4) → tetrabutylammonium diiodoaurate(I) (50481-03-3)

Guidance literature:

In ethanol; at 50 ℃; for 2h;

DOI:10.1002/anie.201803965

Reference yield: 84.0%

tetra-n-butylammonium dibromoaurate(I) (50481-01-1) + 2,4,6-tris(trilfuoromethyl)phenyllithium (444-40-6) → NBu4[Au(I)(2,4,6-tris(trifluoromethyl)phenyl)2]

Guidance literature:

In diethyl ether; under N2; the Au complex was added to freshly prepared soln. of organolithium, mixt. was stirred for 22 h, then 2 drops of water were added; the volatiles were pumped off, residue was extd. with CH2Cl2 and filtered, hexane was added to the filtrate, which was concd. and cooled to -20°C, ppt. was decanted, washed with hexane and dried in vac.; elem. anal.;

DOI:10.1021/om990435z

upstream raw materials:

tetrabutylammonium tetrabromoaurate(III)

Downstream raw materials:

(triethylphosphine)gold(I) bromide

bromo(diphenylphosphine)gold(I)

tetra(n-butyl)ammonium μ-diphenylphosphido-bis{bromogold(I)}

[n-Bu₄N][Au(SC₆H₄OMe-m)2]

Refernces