bromo(diphenylphosphine)gold(I)

Base Information

• Chemical Name: bromo(diphenylphosphine)gold(I)
• CAS No.: 115402-97-6
• Molecular Formula: C₁₂H₁₁AuBrP
• Molecular Weight: 463.064
• Mol file: 115402-97-6.mol

Synonyms:

Chemical Property of bromo(diphenylphosphine)gold(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bromo(diphenylphosphine)gold(I)

There total 2 articles about bromo(diphenylphosphine)gold(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

(tetrahydrothiophene)gold(I) bromide (39929-22-1) + diphenylphosphane (829-85-6) → bromo(diphenylphosphine)gold(I) (115402-97-6)

Guidance literature:

In hexane; dichloromethane; PPh2H is added to a suspension of (AuBr(thtp)) in dichloromethane under nitrogen, soln. is stirred for 15 min, n-hexane is added, pptn.; washing (n-hexane), recrystd. (diethyl ether/n-hexane);

Reference yield: 55.0%

tetra-n-butylammonium dibromoaurate(I) (50481-01-1) + diphenylphosphane (829-85-6) → bromo(diphenylphosphine)gold(I) (115402-97-6)

Guidance literature:

In dichloromethane; N2 atmosphere; addn. of PHPh2 to soln. of Au-complex, stirring (10 min); removal of solvent (vac.), dissolving (CHCl3), crystn. on diffusion of light petroleum (cooling, slow); elem. anal.;

DOI:10.1039/DT9890000907

Reference yield: 80.0%

bromo(diphenylphosphine)gold(I) (115402-97-6) → poly{μ-diphenylphosphido-gold(I)}

Guidance literature:

With pyridine; In dichloromethane; N2 atmosphere; addn. of pyridine to soln. of Au-complex (dropwise, stirring), 5 min, pptn.; sepn. (centrifugation), washing (ether); elem. anal., IR spectroscopy;

DOI:10.1039/DT9890000907

upstream raw materials:

tetra-n-butylammonium dibromoaurate(I)

diphenylphosphane

(tetrahydrothiophene)gold(I) bromide