Iodogold;tetrabutylazanium;iodide

Base Information

• Chemical Name: Iodogold;tetrabutylazanium;iodide
• CAS No.: 50481-03-3
• Molecular Formula: C16H36AuI2N
• Molecular Weight: 693.244
• Mol file: 50481-03-3.mol

Synonyms:

Chemical Property of Iodogold;tetrabutylazanium;iodide

Chemical Property:

• PSA: 0.00000
• LogP: 6.77250
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 12
• Exact Mass: 693.06029
• Heavy Atom Count: 20
• Complexity: 118

Purity/Quality:

95% ^*data from raw suppliers

TETRABUTYLAMMONIUM DIIODOAURATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.[I-].I[Au]

Technology Process of Iodogold;tetrabutylazanium;iodide

There total 4 articles about Iodogold;tetrabutylazanium;iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

tetra-(n-butyl)ammonium iodide (311-28-4) + gold (7440-57-5,457905-15-6) → tetrabutylammonium diiodoaurate(I) (50481-03-3)

Guidance literature:

With I₂; In ethanol; absolute EtOH, granular Au, excess Bu4NI; refluxing for 7 d; decantation, crystn. on cooling to room temp.; elem. anal.;

DOI:10.1039/DT9950001341

Reference yield: 87.0%

tetra-n-butylammonium dibromoaurate(I) (50481-01-1) + tetra-(n-butyl)ammonium iodide (311-28-4) → tetrabutylammonium diiodoaurate(I) (50481-03-3)

Guidance literature:

In ethanol; at 50 ℃; for 2h;

DOI:10.1002/anie.201803965

Reference yield: 77.0%

iodine (7553-56-2,12190-71-5,8031-47-8) + tetra-(n-butyl)ammonium iodide (311-28-4) + gold (7440-57-5,457905-15-6) → tetrabutylammonium diiodoaurate(I) (50481-03-3)

Guidance literature:

In ethanol; for 72h; Reflux; Inert atmosphere; Schlenk technique;

DOI:10.1021/ac402150y

upstream raw materials:

tetra-(n-butyl)ammonium iodide

gold

iodine

tetra-n-butylammonium dibromoaurate(I)

Downstream raw materials:

iodo[tris(2,4,6-trimethoxyphenyl)phosphine]gold(I)

bis(tricyclohexylphosphine)gold(I) iodide

bis(tricyclohexylphosphine)gold(I) iodide, adduct with tricyclohexylphosphine

(L-2)-[(+/-)-(2-aminophenyl)methylphenylphosphine]iodogold(I)