N',P,P-Tris(trimethylsilyl)phosphinimidic amide

Base Information

• Chemical Name: N',P,P-Tris(trimethylsilyl)phosphinimidic amide
• CAS No.: 50732-21-3
• Molecular Formula: C₉H₂₇N₂PSi₃
• Molecular Weight: 278.557
• DSSTox Substance ID: DTXSID80702999
• Wikidata: Q82635050
• Mol file: 50732-21-3.mol

Synonyms:50732-21-3;N',P,P-Tris(trimethylsilyl)phosphinimidic amide;DTXSID80702999

Chemical Property of N',P,P-Tris(trimethylsilyl)phosphinimidic amide

Chemical Property:

• PSA: 48.19000
• LogP: 5.26630
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 280.13761553
• Heavy Atom Count: 15
• Complexity: 263

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[Si](C)(C)N=P(N)([Si](C)(C)C)[Si](C)(C)C

Technology Process of N',P,P-Tris(trimethylsilyl)phosphinimidic amide

There total 2 articles about N',P,P-Tris(trimethylsilyl)phosphinimidic amide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3,4,4-tetrakis(trimethylsilyl)-2-phospha-1-tetrazene (111438-03-0,128336-86-7) → tetrakis(trimethylsilyl)hydrazine (20156-62-1) + N,N,N'-tris(trimethylsilyl)phosphenimidous amide (50732-21-3,65428-75-3) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3)

Guidance literature:

In benzene; at 100 ℃; for 24h;

Reference yield:

N--N,N'-bis(trimethylsilyl)phosphenimidous amide (86211-37-2) → N,N,N'-tris(trimethylsilyl)phosphenimidous amide (50732-21-3,65428-75-3) + N-phenyl-N'-(trimethylsilyl)carbodiimide (30543-46-5) + 2--1-phenyl-3-(trimethylsilyl)-1,3,2-diazaphosphetidin-4-one

Guidance literature:

under 0.02 Torr; Product distribution; Heating;

Reference yield: 100.0%

N,N,N'-tris(trimethylsilyl)phosphenimidous amide (50732-21-3,65428-75-3) + thiophenol (108-98-5) → C15H33N2PSSi3 (79629-83-7)

Guidance literature:

In diethyl ether; at 20 ℃; for 3h;

upstream raw materials:

1,3,4,4-tetrakis(trimethylsilyl)-2-phospha-1-tetrazene

N--N,N'-bis(trimethylsilyl)phosphenimidous amide

Downstream raw materials:

bis(trimethylsilyl)aminodichlorophosphine

2,4-Dichloro-4-phenyl-1,3-bis-trimethylsilanyl-[1,3,2,4]diazaphosphasiletidine

[2-(1,1,1,3,3,3-Hexamethyl-disilazan-2-yl)-1,3-dimethyl-4,4,4-triphenyl-2λ⁵,4λ⁵-[1,3,2,4]diazadiphosphetidin-2-ylidene]-trimethylsilanyl-amine

C₂₁H₄₈N₂O₃P₂Si₃