(Z)-1,2-dicyanoethene-1,2-dithiolate;nickel(3+);tetrabutylazanium

Base Information

• Chemical Name: (Z)-1,2-dicyanoethene-1,2-dithiolate;nickel(3+);tetrabutylazanium
• CAS No.: 55401-12-2
• Molecular Formula: C24H36N5NiS4
• Molecular Weight: 581.53
• European Community (EC) Number: 678-624-3
• Mol file: 55401-12-2.mol

Synonyms:18958-62-8;55401-12-2;(Z)-1,2-dicyanoethene-1,2-dithiolate;nickel(3+);tetrabutylazanium;MFCD00191492;T1415;Tetra-N-butylammonium bis-(maleonitriledithiolato)nickel(ii)complex

Chemical Property of (Z)-1,2-dicyanoethene-1,2-dithiolate;nickel(3+);tetrabutylazanium

Chemical Property:

• PSA: 95.16000
• LogP: 5.68152
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 12
• Exact Mass: 580.120698
• Heavy Atom Count: 34
• Complexity: 545

Purity/Quality:

98% ^*data from raw suppliers

Tetrabutylammoniumbis(maleonitriledithiolato)nickel(III) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.C(#N)C(=C(C#N)[S-])[S-].C(#N)C(=C(C#N)[S-])[S-].[Ni+3]
• Isomeric SMILES: CCCC[N+](CCCC)(CCCC)CCCC.C(#N)/C(=C(/[S-])\C#N)/[S-].C(#N)/C(=C(/[S-])\C#N)/[S-].[Ni+3]
• Uses: Tetrabutylammonium bis(maleonitriledithiolato)nickel(III) (CAS# 55401-12-2) is an organometallic catalyst used in proton-reduction reactions, and is used as a building block in the preparation of iron(II) ferrocenylethenylbis(pyrazolyl)pyridine complexes.

Technology Process of (Z)-1,2-dicyanoethene-1,2-dithiolate;nickel(3+);tetrabutylazanium

There total 1 articles about (Z)-1,2-dicyanoethene-1,2-dithiolate;nickel(3+);tetrabutylazanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[tetrabutylammonium]2 bis(cis-1,2-dicyanoethene-1,2-dithiolato)nickelate(II) (18958-57-1) → tetrabutylammonium bis(maleonitriledithiolato)nickelate(III) (55401-12-2)

Guidance literature:

With I₂;

DOI:10.1021/ic50010a031

Reference yield:

tetrabutylammonium bis(maleonitriledithiolato)nickelate(III) (55401-12-2) + acetonitrile (75-05-8,26809-02-9) + 4-(2,4,6-triphenylpyridinium)-2,2,5,5-tetramethyl-1-piperidinyloxy tetrafluoroborate → (TEMPO-substituted 2,4,6-triphenylpyridinium)4[Ni(maleonitriledithiolate)2]5(1-)*2(acetonitrile)

Guidance literature:

In acetonitrile; fluoroborate compound reacted with Ni-compound in CH3CN;

DOI:10.1016/j.poly.2006.10.041

Reference yield:

tetrabutylammonium bis(maleonitriledithiolato)nickelate(III) (55401-12-2) + iron(II) tetrafluoroborate hexahydrate + 1-(2-(1,3-dithiol-2-ylidene)-1,3-dithiolyl)-2-(2,6-bis(1-pyrazolyl)pyridyl)ethylene (1279123-02-2) + tetrabutylammonium tetrafluoroborate (429-42-5) + benzonitrile (100-47-0) → [Fe(1-(2-(1,3-dithiol-2ylidene)-1,3-dithiolyl)-2-(2,6-bis(1-pyrazolyl)pyridyl)ethylene)2][Ni(maleonitriledithiolate)2]2(BF4)*PhCN

Guidance literature:

In benzonitrile; Electrochem. Process; under N2; Fe compd. reacted with ligand in PhCN; Ni complex and Bu4NBF4 added; subjected to galvanostatic oxidn.; elem. anal.;

DOI:10.1039/c0dt01092h

upstream raw materials:

[tetrabutylammonium]2 bis(cis-1,2-dicyanoethene-1,2-dithiolato)nickelate(II)

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