Phosphanylidynemanganese

Base Information

• Chemical Name: Phosphanylidynemanganese
• CAS No.: 12032-78-9
• Deprecated CAS: 480452-69-5
• Molecular Formula: MnP
• Molecular Weight: 85.9118
• European Community (EC) Number: 234-777-4
• Wikidata: Q4492128
• Mol file: 12032-78-9.mol

Synonyms:phosphanylidynemanganese;12032-78-9;EINECS 234-777-4;Q4492128

Chemical Property of Phosphanylidynemanganese

Chemical Property:

• Melting Point: 1147°C
• Density: 5.490
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 85.911805
• Heavy Atom Count: 2
• Complexity: 10

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: P#[Mn]

Technology Process of Phosphanylidynemanganese

There total 13 articles about Phosphanylidynemanganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

dimanganese decacarbonyl (10170-69-1) + Tris(trimethylsilyl)phosphane (15573-38-3) → manganese phosphide (12032-78-9,12397-32-9)

Guidance literature:

With trioctylphosphine oxide; myristic acid; In further solvent(s); injecting of P(SiMe3)3 into soln. of Mn2(CO)10 in trioctylphosphine oxide with myristic acid at 100°C; heating at 220°C for 1 day; addn. of equal volume of pyridine and then hexane, pptn.;

DOI:10.1021/ja038037h

Reference yield:

manganese (7439-96-5) + phosphorus → manganese phosphide (12032-78-9,12397-32-9)

Guidance literature:

In melt; at 1200 ℃; for 2h; under 7500750 Torr; Glovebox; Inert atmosphere;

DOI:10.1016/j.jallcom.2017.07.247

Reference yield:

manganese (7439-96-5) + phosphorous → manganese phosphide (12032-78-9,12397-32-9)

Guidance literature:

heating 10-12 h at 600°C;

upstream raw materials:

manganese

manganese(IV) oxide

gallium phosphide

tert-butylphosphine

Downstream raw materials:

manganese(II) iodide

phosphorous

hydrogen

Refernces

• 1、 Zhigadlo, Nikolai D.,Barbero, Nicolo,Shiroka, Toni. "Growth of bulk single-crystal MnP helimagnet and its structural and NMR characterization". . p. 1027 - 1034. Retrieved 2017.
• 2、 Dunaev,Zvonkov,Danilov,Vikhrova,Drozdov,Drozdov,Suchkov. "Composition and structural perfection of (AIII,Mn)BV and MnBV (A = Ga, In; B = Sb, As, P) nanolayers". . p. 553 - 558. Retrieved 2012.
• 3、 Perera, Susanthri C.,Tsoi, Georgy,Wenger, Lowell E.,Brock, Stephanie L.. "Synthesis of MnP Nanocrystals by Treatment of Metal Carbonyl Complexes with Phosphines: A New, Versatile Route to Nanoscale Transition Metal Phosphides". . p. 13960 - 13961. Retrieved 2003.
• 4、 Park, Jongnam,Koo, Bonil,Yoon, Ki Youl,Hwang, Yosun,Kang, Misun,Park, Je-Geun,Hyeon, Taeghwan. "Generalized synthesis of metal phosphide nanorods via thermal decomposition of continuously delivered metal-phosphine complexes using a syringe pump". . p. 8433 - 8440. Retrieved 2005.
• 5、 Grosvenor, Andrew P.,Wik, Stephen D.,Cavell, Ronald G.,Mar, Arthur. "Examination of the bonding in binary transition-metal monophosphides MP (M = Cr, Mn, Fe, Co) by X-ray photoelectron spectroscopy". . p. 8988 - 8998. Retrieved 2005.
• 6、 Kawakatsu, Shoya,Kakihana, Masashi,Nakashima, Miho,Amako, Yasushi,Nakamura, Ai,Aoki, Dai,Takeuchi, Tetsuya,Harima, Hisatomo,Hedo, Masato,Nakama, Takao,ōnuki, Yoshichika. "De Haas–Van Alphen experiment and Fermi surface properties in field-induced ferromagnetic state of MNP". . . Retrieved 2019.
• 7、 Owens, Frank J.. "Ferromagnetism above room temperature in bulk sintered gallium phosphide doped with manganese". . p. 793 - 796. Retrieved 2005.
• 8、 Booth, Ryan A.,Marinescu, Melania,Liu, JinFang,Majetich, Sara A.. "Preferential crystallographic alignment in polycrystalline MnP". . p. 2571 - 2574. Retrieved 2010.