Di-u-acetatobis-(1,5-cyclooctadiene)-dirhodium

Base Information

• Chemical Name: Di-u-acetatobis-(1,5-cyclooctadiene)-dirhodium
• CAS No.: 12097-36-8
• Molecular Formula: C20H30 O4 Rh2
• Molecular Weight: 540.267

Synonyms:Rhodium,bis(acetato)bis(1,5-cyclooctadiene)di- (7CI); Rhodium, bis[m-(acetato-O:O')]bis[(1,2,5,6-h)-1,5-cyclooctadiene]di-;1,5-Cyclooctadiene, rhodium complex; Bis((m-acetato)(1,5-cyclooctadiene)rhodium); Bis(m-acetato)bis(cyclooctadiene)dirhodium;Bis[(acetato)(h4-1,5-cyclooctadiene)rhodium];Bis[acetato(1,5-cyclooctadiene)rhodium]; Diacetatobis(1,5-cyclooctadiene)dirhodium

Chemical Property of Di-u-acetatobis-(1,5-cyclooctadiene)-dirhodium

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

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Technology Process of Di-u-acetatobis-(1,5-cyclooctadiene)-dirhodium

There total 4 articles about Di-u-acetatobis-(1,5-cyclooctadiene)-dirhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

rhodium{C6H3(CH2NMe2)2-o,o'}(1,5-cyclooctadiene) (115338-66-4) → {m-(Me2(H)NCH2)2C6H4}(OAc)2 (115338-76-6) + {rhodium(OAc)(1,5-cyclooctadiene)}2 (12097-36-8)

Guidance literature:

With CH₃COOH; In benzene; stirring for 5 min; addn. of water, sepn. of layers, evapn. to dryness; Rh complex from benzene extract, aryl compound from water layer;

DOI:10.1021/om00099a010

Reference yield: 66.0%

chloro(1,5-cyclooctadiene)rhodium(I) dimer + potassium acetate (127-08-2) → di-μ-acetato-bis(η4-1,5-cyclooctadiene)dirhodium(I) (12097-36-8)

Guidance literature:

In acetone; Inert atmosphere; Reflux;

DOI:10.1021/ja511445x

Reference yield:

[(CH2CHCHCH2)2RhO]2 (73456-63-0) → [Rh(COD)OAc]2 (12097-36-8)

Guidance literature:

With acetic acid; In neat (no solvent); byproducts: H2O2; IR, NMR;

DOI:10.1021/ja00525a060

upstream raw materials:

rhodium{C₆H₃(CH₂NMe₂)2-o,o'}(1,5-cyclooctadiene)

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

potassium acetate

[(CH₂CHCHCH₂)2RhO]2

Downstream raw materials:

(η4-cycloocta-1,5-diene)(rac-N-phenylglycinato-κ(2)N,O)rhodium(I)

(η4-cycloocta-1,5-diene)(N-(o-tolyl)-2-oxo-1-naphthaldiminato-κ(2)N,O)rhodium(I)

[Rh(η4-cod){3-((R)-(4-methoxyphenyl)-ethylimino)-3H-indol-2-olato}]

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