MANGANESE PHOSPHIDE

Base Information

• Chemical Name: MANGANESE PHOSPHIDE
• CAS No.: 12397-32-9
• Molecular Formula: Mn3P2
• Molecular Weight: 226.76
• Mol file: 12397-32-9.mol

Synonyms:MANGANESE PHOSPHIDE

Chemical Property of MANGANESE PHOSPHIDE

Chemical Property:

• Melting Point: 1095℃ [AES93]
• PSA: 46.94000
• Density: 5.120
• LogP: 1.18700

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of MANGANESE PHOSPHIDE

There total 14 articles about MANGANESE PHOSPHIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

dimanganese decacarbonyl (10170-69-1) + Tris(trimethylsilyl)phosphane (15573-38-3) → manganese phosphide (12032-78-9,12397-32-9)

Guidance literature:

With trioctylphosphine oxide; myristic acid; In further solvent(s); injecting of P(SiMe3)3 into soln. of Mn2(CO)10 in trioctylphosphine oxide with myristic acid at 100°C; heating at 220°C for 1 day; addn. of equal volume of pyridine and then hexane, pptn.;

DOI:10.1021/ja038037h

Reference yield:

manganese (7439-96-5) + phosphorus → manganese phosphide (12032-78-9,12397-32-9)

Guidance literature:

In melt; at 1200 ℃; for 2h; under 7500750 Torr; Glovebox; Inert atmosphere;

DOI:10.1016/j.jallcom.2017.07.247

Reference yield:

manganese (7439-96-5) + phosphorous → manganese phosphide (12032-78-9,12397-32-9)

Guidance literature:

heating 10-12 h at 600°C;

upstream raw materials:

manganese

manganese(IV) oxide

gallium phosphide

tert-butylphosphine

Downstream raw materials:

manganese(II) iodide

phosphorous

hydrogen

Refernces

• 1、 Cao, Guang-Han,Feng, Zhifa,Hu, Bingfeng,Jing, Qiang,Li, Baizhuo,Liu, Bo,Liu, Zichen,Luo, Huiqian,Ma, Jie,Mao, Huican,Mei, Yuxue,Ren, Qingyong,Ren, Zhi,Shao, Yeting,Sun, Yuping,Tan, Shugang,Wang, Cao,Wang, Zhicheng,Xia, Yuanhua,Zhang, Fuxiang. "ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects". . . Retrieved 2020/03/10.
• 2、 Zhigadlo, Nikolai D.,Barbero, Nicolo,Shiroka, Toni. "Growth of bulk single-crystal MnP helimagnet and its structural and NMR characterization". . p. 1027 - 1034. Retrieved 2017/08/02.