D-myo-Inositol 4-monophosphate ammonium salt

Base Information

• Chemical Name: D-myo-Inositol 4-monophosphate ammonium salt
• CAS No.: 69256-52-6
• Molecular Formula: C6H13O9P
• Molecular Weight: 294.2
• Mol file: 69256-52-6.mol

Synonyms:D-MYO-INOSITOL 4-MONOPHOSPHATE AMMONIUM SALT

Chemical Property of D-myo-Inositol 4-monophosphate ammonium salt

Chemical Property:

• PSA: 177.72000
• LogP: -3.71760
• Storage Temp.: ?20°C

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of D-myo-Inositol 4-monophosphate ammonium salt

There total 50 articles about D-myo-Inositol 4-monophosphate ammonium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,4,5-tri-O-acetyl-3,6-di-O-benzyl-2-O-(3-oxo-1,5-dihydro-3λ5-2,4,3-benzodioxaphosphepin-3-yl)-D-myo-inositol (864372-89-4) → myo-Inositol 2-phosphate (573-35-3,633-88-5,2831-74-5,4956-00-7,7336-80-3,13004-72-3,13331-65-2,15421-51-9,21667-10-7,26277-10-1,26545-79-9,34218-99-0,34219-00-6,34219-01-7,35275-50-4,46495-37-8,46495-38-9,46495-39-0,57652-30-9,69256-52-6,84414-08-4,111901-84-9)

Guidance literature:

1,4,5-tri-O-acetyl-3,6-di-O-benzyl-2-O-(3-oxo-1,5-dihydro-3λ⁵-2,4,3-benzodioxaphosphepin-3-yl)-D-myo-inositol; With hydrogen; palladium on activated charcoal; In ethanol; water; at 20 ℃;

With sodium hydroxide; water; for 4h; cooling;

DOI:10.1002/ejoc.200400911

Reference yield: 60.0%

C39H47O9P → (+/-) myo-inositol 4-phosphate (573-35-3,633-88-5,2831-74-5,4956-00-7,7336-80-3,13004-72-3,13331-65-2,15421-51-9,21667-10-7,26277-10-1,26545-79-9,34218-99-0,34219-00-6,34219-01-7,35275-50-4,46495-37-8,46495-38-9,46495-39-0,57652-30-9,69256-52-6,84414-08-4,111901-84-9)

Guidance literature:

With hydrogen; palladium on activated charcoal; In ethanol; water; at 25 ℃; under 2585.7 Torr;

DOI:10.1039/c39870000314

Reference yield:

[3H]-Phytic acid → D-myo-inositol (87-89-8) + myo-Inositol 2-phosphate (573-35-3,633-88-5,2831-74-5,4956-00-7,7336-80-3,13004-72-3,13331-65-2,15421-51-9,21667-10-7,26277-10-1,26545-79-9,34218-99-0,34219-00-6,34219-01-7,35275-50-4,46495-37-8,46495-38-9,46495-39-0,57652-30-9,69256-52-6,84414-08-4,111901-84-9) + Phosphoric acid mono-((1R,2S,3S,4S,5R,6S)-2,3,6-trihydroxy-4,5-bis-phosphonooxy-cyclohexyl) ester + Phosphoric acid mono-((1S,2R,3R,4R,5R,6R)-2,3-dihydroxy-4,5,6-tris-phosphonooxy-cyclohexyl) ester

Guidance literature:

With phytase from wheat bran of T_. aestivum L_. cv. Nourin No_. 61; water; In acetate buffer; at 37 ℃; pH=5.5; Product distribution;

DOI:10.1271/bbb.64.995

upstream raw materials:

2-O-phosphono-1,3,4,5,6-penta-O-acetyl-myo-inositol

D-myo-inositol

3,3,7,7-tetramethyl-2,8-dioxa-5-aza-1λ³-phosphabicyclo(3,3,0)octane

4,6-di-O-benzyl-myo-inositol 2-dibenzylphosphate

Downstream raw materials:

DL-O¹,O²-hydroxyphosphoryl-myo-inositol

inositol

phosphoric acid

Refernces

• 1、 Podeschwa, Michael A. L.,Plettenburg, Oliver,Altenbach, Hans-Josef. "Flexible stereo- and regioselective synthesis of myo-inositol phosphates (part 1): Via symmetrical conduritol B derivatives". . p. 3101 - 3115. Retrieved 2007/10/03.
• 2、 Sureshan, Kana M.,Watanabe, Yutaka. "An efficient route to optically active inositol derivatives via the resolution of myo-inositol 1,3,5-orthoformate: A short synthesis of D-myo-inositol-4-phosphate". . p. 1193 - 1198. Retrieved 2007/10/03.