ABSCISIC ACID METHYLESTER

Base Information

• Chemical Name: ABSCISIC ACID METHYLESTER
• CAS No.: 6901-96-8
• Molecular Formula: C16H22O4
• Molecular Weight: 278.348
• Mol file: 6901-96-8.mol

Synonyms:ABSCISIC ACID METHYLESTER

Chemical Property of ABSCISIC ACID METHYLESTER

Chemical Property:

• PSA: 63.60000
• LogP: 2.33830
• Storage Temp.: Room Temperature, under inert atmosphere
• Solubility.: Chloroform, Methanol

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: Abscisic Acid Methyl Ester is an intermediate in the synthesis of Abscisic Aldehyde (A110005) which is an intermediate in the biosynthesis of the plant hormone Abscisic Acid (A110000). It is also the biosynthetic precursor of phytohormone Abscisic Acid (ABA), which regulates stress responses and controls numerous aspects of plant growth and development.

Technology Process of ABSCISIC ACID METHYLESTER

There total 45 articles about ABSCISIC ACID METHYLESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diazomethane (186581-53-3,908094-01-9,334-88-3) + Abscisic acid (2228-72-0,6755-41-5,7773-56-0,14375-45-2,14398-53-9,14674-85-2,40331-02-0,52392-36-6,72029-68-6,72029-69-7,113349-29-4,21293-29-8) → (S)-methyl abscisate (6901-90-2,6901-96-8,14398-52-8,15734-36-8,15734-37-9,20496-94-0,30816-18-3,60102-39-8,79434-13-2,93164-18-2,132340-88-6,132488-74-5,7200-31-9)

Guidance literature:

In diethyl ether; acetone; at 0 ℃; for 0.0333333h;

Reference yield: 95.0%

methanol (67-56-1) + Abscisic acid (2228-72-0,6755-41-5,7773-56-0,14375-45-2,14398-53-9,14674-85-2,40331-02-0,52392-36-6,72029-68-6,72029-69-7,113349-29-4,21293-29-8) → (S)-methyl abscisate (6901-90-2,6901-96-8,14398-52-8,15734-36-8,15734-37-9,20496-94-0,30816-18-3,60102-39-8,79434-13-2,93164-18-2,132340-88-6,132488-74-5,7200-31-9)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 17h;

DOI:10.1016/j.phytol.2015.04.015

Reference yield: 94.0%

Abscisic acid (2228-72-0,6755-41-5,7773-56-0,14375-45-2,14398-53-9,14674-85-2,40331-02-0,52392-36-6,72029-68-6,72029-69-7,113349-29-4,21293-29-8) + dimethyl sulfate (77-78-1) → (S)-methyl abscisate (6901-90-2,6901-96-8,14398-52-8,15734-36-8,15734-37-9,20496-94-0,30816-18-3,60102-39-8,79434-13-2,93164-18-2,132340-88-6,132488-74-5,7200-31-9)

Guidance literature:

With potassium carbonate; In acetone; for 1h; Heating;

DOI:10.1080/00397919708006821

upstream raw materials:

diazomethane

Abscisic acid

(+)-(1'R)-(2Z,4E)-4'-Oxo-α-ionylideneacetic acid

(2Z,4E)-methyl 5-(1',4'-dihydroxy-2',6',6'-trimethyl-2'-cyclohexen-1'-yl)-3-methylpenta-2,4-dienoate

Downstream raw materials:

methyl (1'S,2'S)-(+)-2',3'-dihydro-4'-hydroxyabscisate

methanol

Abscisic acid