2-Bromo-6-methyl-4-nitro-1-oxidopyridin-1-ium

Base Information Edit

Chemical Name:2-Bromo-6-methyl-4-nitro-1-oxidopyridin-1-ium
CAS No.:60323-99-1
Molecular Formula:C6H5BrN2O3
Molecular Weight:233.021
Hs Code.:2933399090
DSSTox Substance ID:DTXSID00372855
Wikidata:Q82160784
Mol file:60323-99-1.mol

Synonyms:60323-99-1;2-Bromo-6-methyl-4-nitropyridine 1-oxide;2-bromo-6-methyl-4-nitro-1-oxidopyridin-1-ium;2-BROMO-6-METHYL-4-NITROPYRIDIN-1-OXIDE;SCHEMBL942208;DTXSID00372855;FXJATGFTSNBVNK-UHFFFAOYSA-N;AKOS004906940;2-bromo-6-methyl-4-nitropyridine1-oxide;2-bromo-6-methyl-4-nitropyridine N-oxide;2-bromo-6-methyl-4-nitro-pyridine 1-oxide;FT-0687923;6-Bromo-2-methyl-4-Nitropyridine-n-oxide,97%;2-?bromo-?6-?methyl-?4-?nitropyridine 1-?oxide;A928668;J-400276;2-Bromo-6-methyl-4-nitro-1-oxo-1lambda~5~-pyridine;2-BROMO-6-METHYL-4-NITROPYRIDIN-1-IUM-1-OLATE

Suppliers and Price of 2-Bromo-6-methyl-4-nitro-1-oxidopyridin-1-ium

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
6-BROMO-2-METHYL-4-NITROPYRIDINE-N-OXIDE 95.00%
5G
$ 1976.78

American Custom Chemicals Corporation
6-BROMO-2-METHYL-4-NITROPYRIDINE-N-OXIDE 95.00%
1G
$ 1067.22

American Custom Chemicals Corporation
6-BROMO-2-METHYL-4-NITROPYRIDINE-N-OXIDE 95.00%
100MG
$ 206.85

Total 8 raw suppliers

Chemical Property of 2-Bromo-6-methyl-4-nitro-1-oxidopyridin-1-ium Edit

Chemical Property:

Vapor Pressure:1.51E-07mmHg at 25°C
Melting Point:131 °C
Refractive Index:1.643
Boiling Point:440.6°C at 760 mmHg
PKA:-2.34±0.10(Predicted)
Flash Point:220.2°C
PSA：71.28000
Density:1.85g/cm³
LogP:2.61740
XLogP3:1.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:0
Exact Mass:231.94835
Heavy Atom Count:12
Complexity:184

Purity/Quality:

98% ^*data from raw suppliers

6-BROMO-2-METHYL-4-NITROPYRIDINE-N-OXIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 20/21/22
Safety Statements: 36/37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=CC(=[N+]1[O-])Br)[N+](=O)[O-]

Technology Process of 2-Bromo-6-methyl-4-nitro-1-oxidopyridin-1-ium

There total 3 articles about 2-Bromo-6-methyl-4-nitro-1-oxidopyridin-1-ium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 91668-84-7
2-bromo-6-methylpyridine N-oxide

: 60323-99-1
2-bromo-6-methyl-4-nitro-pyridine-1-oxide

Guidance literature:: With sulfuric acid; nitric acid; at 0 - 85 ℃; for 16h;

Reference yield:

: 5315-25-3
2-bromo-6-methylpyridine

: 60323-99-1
2-bromo-6-methyl-4-nitro-pyridine-1-oxide

Guidance literature:: Multi-step reaction with 2 steps

1: 3-chloro-benzenecarboperoxoic acid / chloroform / 18 h / 65 °C / Inert atmosphere

2: nitric acid; sulfuric acid / 16 h / 0 - 100 °C

With sulfuric acid; nitric acid; 3-chloro-benzenecarboperoxoic acid; In chloroform;
DOI:10.1039/c2cc35247h