4-Triethoxysilylaniline

Base Information

• Chemical Name: 4-Triethoxysilylaniline
• CAS No.: 7003-80-7
• Molecular Formula: C12H21NO3Si
• Molecular Weight: 255.389
• DSSTox Substance ID: DTXSID40431233
• Nikkaji Number: J1.238.310J
• Wikidata: Q82245067
• Mol file: 7003-80-7.mol

Synonyms:4-triethoxysilylaniline;7003-80-7;4-(triethoxysilyl)aniline;p-aminophenyltriethoxysilane;Benzenamine, 4-(triethoxysilyl)-;SCHEMBL483106;DTXSID40431233;AKOS015916735

Chemical Property of 4-Triethoxysilylaniline

Chemical Property:

• Boiling Point: 296.133 °C at 760 mmHg
• PKA: 4.03±0.10(Predicted)
• Flash Point: 132.897 °C
• PSA: 53.71000
• Density: 1.037g/cm³
• LogP: 2.10540
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 7
• Exact Mass: 255.12907007
• Heavy Atom Count: 17
• Complexity: 191

Purity/Quality:

99%, ^*data from raw suppliers

4-TRIETHOXYSILYLANILINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCO[Si](C1=CC=C(C=C1)N)(OCC)OCC

Technology Process of 4-Triethoxysilylaniline

There total 5 articles about 4-Triethoxysilylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

Triethoxysilane (998-30-1) + p-aminoiodobenzene (540-37-4) → p-aminophenyltriethoxysilane (7003-80-7)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In 1-methyl-pyrrolidin-2-one; at 20 ℃; for 20h;

DOI:10.1016/j.tet.2007.08.011

Reference yield: 77.0%

Triethoxysilane (998-30-1) + p-aminoiodobenzene (540-37-4) → p-aminophenyltriethoxysilane (7003-80-7) + aniline (62-53-3)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; johnphos; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In 1-methyl-pyrrolidin-2-one; at 20 ℃; for 12h;

DOI:10.1021/jo010621q

Reference yield: 38.0%

Triethoxysilane (998-30-1) + 4-bromo-aniline (106-40-1) → p-aminophenyltriethoxysilane (7003-80-7) + aniline (62-53-3)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; johnphos; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In 1-methyl-pyrrolidin-2-one; at 20 ℃; for 2h;

DOI:10.1021/jo010621q

upstream raw materials:

tetraethoxy orthosilicate

4-bromo-aniline

Triethoxysilane

p-aminoiodobenzene

Downstream raw materials:

diallyl(4-aminophenyl)ethoxysilane

tert-butyl 3-(4-aminophenyl) azetidine-1-carboxylate

3-(4-aminophenyl)cyclohexene

Refernces

• 1、 Maegawa, Yoshifumi,Nagano, Toyohiro,Yabuno, Tatsuya,Nakagawa, Hiroki,Shimada, Toyoshi. "Preparation of functionalized aryl(diallyl)ethoxysilanes and their palladium-catalyzed coupling reactions giving sol-gel precursors". . p. 11467 - 11474. Retrieved 2008/03/12.
• 2、 -. "Diamino compounds and their production method". . . Retrieved 2008/06/13.