4,4'-[Decane-1,10-diylbis(oxy)]bis(3-phenoxyphenol)

Base Information

• Chemical Name: 4,4'-[Decane-1,10-diylbis(oxy)]bis(3-phenoxyphenol)
• CAS No.: 70856-53-0
• Molecular Formula: C34H38O4
• Molecular Weight: 358.478
• DSSTox Substance ID: DTXSID80697573
• Wikidata: Q82627506
• Mol file: 70856-53-0.mol

Synonyms:70856-53-0;4,4'-[Decane-1,10-diylbis(oxy)]bis(3-phenoxyphenol);4-[10-(4-hydroxy-2-phenoxyphenoxy)decoxy]-3-phenoxyphenol;DTXSID80697573;A837011;4-[10-(4-oxidanyl-2-phenoxy-phenoxy)decoxy]-3-phenoxy-phenol

Chemical Property of 4,4'-[Decane-1,10-diylbis(oxy)]bis(3-phenoxyphenol)

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.552
• Boiling Point: 536.812°C at 760 mmHg
• Flash Point: 278.454°C
• PSA: 58.92000
• Density: 1.095g/cm³
• LogP: 5.67640
• XLogP3: 9.5
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 17
• Exact Mass: 542.26683893
• Heavy Atom Count: 40
• Complexity: 580

Purity/Quality:

97% ^*data from raw suppliers

1,10-BIS-(4-HYDROXYDIPHENOXY)DECANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OC2=C(C=CC(=C2)O)OCCCCCCCCCCOC3=C(C=C(C=C3)O)OC4=CC=CC=C4

Technology Process of 4,4'-[Decane-1,10-diylbis(oxy)]bis(3-phenoxyphenol)

There total 6 articles about 4,4'-[Decane-1,10-diylbis(oxy)]bis(3-phenoxyphenol) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

1,10-Bis(p-formyloxyphenoxy)decane (189388-92-9) → α-(Hydrogen)-ω-(hydroxy)-(oxy-1,4-phenyleneoxy-1,10-decamethyleneoxy-1,4-phenylene) (70856-53-0)

Guidance literature:

With sodium hydroxide; In ethanol; for 12h; Heating;

DOI:10.1080/00304949709355193

Reference yield: 33.0%

1,10-dibromodecane (4101-68-2) + hydroquinone (123-31-9,8027-02-9) → α-(Hydrogen)-ω-(hydroxy)-(oxy-1,4-phenyleneoxy-1,10-decamethyleneoxy-1,4-phenylene) (70856-53-0)

Guidance literature:

hydroquinone; With potassium carbonate; In acetonitrile; at 85 ℃; Inert atmosphere;

1,10-dibromodecane; In acetonitrile; for 12h; Inert atmosphere;

DOI:10.1080/10610278.2018.1539228

Reference yield: 33.0%

4-Benzyloxyphenol (103-16-2) + 1,10-dibromodecane (4101-68-2) → α-(Hydrogen)-ω-(hydroxy)-(oxy-1,4-phenyleneoxy-1,10-decamethyleneoxy-1,4-phenylene) (70856-53-0)

Guidance literature:

4-Benzyloxyphenol; 1,10-dibromodecane; With potassium carbonate; In acetone; for 72h; Reflux;

With palladium 10% on activated carbon; hydrogen; In methanol; chloroform; at 20 ℃; under 760.051 Torr;

DOI:10.1021/jo2000397

upstream raw materials:

1,10-Bis(p-formyloxyphenoxy)decane

α-(Benzyl)-ω-(benzyloxy)-(oxy-1,4-phenyleneoxy-1,10-decamethyleneoxy-1,4-phenylene)

4-Benzyloxyphenol

4,4'-[decane-1,10-diylbis(oxy)]dibenzaldehyde

Downstream raw materials:

C₄₆H₅₈O₈

C₅₆H₇₈O₈

C₄₀H₄₆O₈

C₄₄H₅₄O₈