N-METHYL-1-NAPHTHYLAMINE HYDROCHLORIDE

Base Information

• Chemical Name: N-METHYL-1-NAPHTHYLAMINE HYDROCHLORIDE
• CAS No.: 4643-36-1
• Molecular Formula: C11H11 N . Cl H
• Molecular Weight: 193.67300
• Hs Code.: 2921450090
• Mol file: 4643-36-1.mol

Synonyms:1-Naphthalenamine,N-methyl-, hydrochloride (9CI); 1-Naphthylamine, N-methyl-, hydrochloride(8CI); N-Methyl-1-naphthylamine hydrochloride; N-Methyl-a-naphthylamine hydrochloride

Chemical Property of N-METHYL-1-NAPHTHYLAMINE HYDROCHLORIDE

Chemical Property:

• Vapor Pressure: 0.000156mmHg at 25°C
• Melting Point: 177oC
• Boiling Point: 326.5oC at 760 mmHg
• Flash Point: 151.3oC
• PSA: 12.03000
• LogP: 3.75650

Purity/Quality:

98%,99%, ^*data from raw suppliers

N-Methyl-1-naphthylamine Hydrochloride ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-METHYL-1-NAPHTHYLAMINE HYDROCHLORIDE

There total 2 articles about N-METHYL-1-NAPHTHYLAMINE HYDROCHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

methanol (67-56-1) + 1-amino-naphthalene (134-32-7) → N-methyl-1-naphthylamine hydrochloride (4643-36-1)

Guidance literature:

methanol; 1-amino-naphthalene; With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); potassium tert-butylate; at 150 ℃; for 5h; Inert atmosphere; Autoclave;

With hydrogenchloride; In methanol; water;

DOI:10.1021/acs.orglett.8b01449

Reference yield:

→ N-methyl-1-naphthylamine hydrochloride (4643-36-1)

Guidance literature:

Tosylat IX, HCl;

Reference yield: 80.0%

N-methyl-1-naphthylamine hydrochloride (4643-36-1) + phenyl isocyanate (103-71-9) → C18H16N2O

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1002/anie.201702169

upstream raw materials:

methanol

1-amino-naphthalene

Refernces