3-methoxy-7-methyl-7-phenylthio-4bα,5,6,7,8,8a,9,10-octahydro-6α,8aα-ethanophenanthrene

Base Information

Chemical Name:3-methoxy-7-methyl-7-phenylthio-4bα,5,6,7,8,8a,9,10-octahydro-6α,8aα-ethanophenanthrene
CAS No.:98115-52-7
Molecular Formula:C₂₄H₂₈OS
Molecular Weight:364.552
Hs Code.:

Synonyms:

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Chemical Property of 3-methoxy-7-methyl-7-phenylthio-4bα,5,6,7,8,8a,9,10-octahydro-6α,8aα-ethanophenanthrene

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Technology Process of 3-methoxy-7-methyl-7-phenylthio-4bα,5,6,7,8,8a,9,10-octahydro-6α,8aα-ethanophenanthrene

There total 16 articles about 3-methoxy-7-methyl-7-phenylthio-4bα,5,6,7,8,8a,9,10-octahydro-6α,8aα-ethanophenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1199-31-1
1-cyano-5-methoxybenzocyclobutane

: 98115-52-7,98169-17-6
3-methoxy-7-methyl-7-phenylthio-4bβ,5,6,7,8,8a,9,10-octahydro-6α,8aα-ethanophenanthrene

Guidance literature:: Multi-step reaction with 7 steps

1: 81 percent / LDA / tetrahydrofuran; hexamethylphosphoric acid triamide / 1 h / -78 °C

2: 73 percent / toluene-p-sulphonic acid / benzene / 2 h / Heating

3: 80 percent / liq. NH₃, sodium / ethanol; tetrahydrofuran / 3 h / -78 °C

4: 78 percent / 10percent HCl / methanol / 5 h / Ambient temperature

5: 52 percent / Et₃N / 12 h / Ambient temperature

6: 62 percent / tetrahydrofuran / 1 h / 0 °C

7: various solvent(s) / 5 h / Heating

With hydrogenchloride; ammonia; sodium; triethylamine; lithium diisopropyl amide; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; ethanol; benzene;

Reference yield:

: 1199-31-1
1-cyano-5-methoxybenzocyclobutane

: 98115-52-7,98169-17-6
3-methoxy-7-methyl-7-phenylthio-4bα,5,6,7,8,8a,9,10-octahydro-6α,8aα-ethanophenanthrene

Guidance literature:: Multi-step reaction with 7 steps

1: 81 percent / LDA / tetrahydrofuran; hexamethylphosphoric acid triamide / 1 h / -78 °C

2: 73 percent / toluene-p-sulphonic acid / benzene / 2 h / Heating

3: 80 percent / liq. NH₃, sodium / ethanol; tetrahydrofuran / 3 h / -78 °C

4: 78 percent / 10percent HCl / methanol / 5 h / Ambient temperature

5: 52 percent / Et₃N / 12 h / Ambient temperature

6: 62 percent / tetrahydrofuran / 1 h / 0 °C

7: various solvent(s) / 5 h / Heating

With hydrogenchloride; ammonia; sodium; triethylamine; lithium diisopropyl amide; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; ethanol; benzene;

Reference yield:

: 98115-47-0
1-cyano-5-methoxy-1-(2-methyl-4-oxocyclohex-1-enylmethyl)-1,2-dihydrocyclobutabenzene

: 98115-52-7,98169-17-6
3-methoxy-7-methyl-7-phenylthio-4bβ,5,6,7,8,8a,9,10-octahydro-6α,8aα-ethanophenanthrene

Guidance literature:: Multi-step reaction with 6 steps

1: 73 percent / toluene-p-sulphonic acid / benzene / 2 h / Heating

2: 80 percent / liq. NH₃, sodium / ethanol; tetrahydrofuran / 3 h / -78 °C

3: 78 percent / 10percent HCl / methanol / 5 h / Ambient temperature

4: 52 percent / Et₃N / 12 h / Ambient temperature

5: 62 percent / tetrahydrofuran / 1 h / 0 °C

6: various solvent(s) / 5 h / Heating

With hydrogenchloride; ammonia; sodium; triethylamine; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; ethanol; benzene;