1-cyano-5-methoxy-1-(2-methyl-4-oxocyclohex-1-enylmethyl)-1,2-dihydrocyclobutabenzene

Base Information

Chemical Name:1-cyano-5-methoxy-1-(2-methyl-4-oxocyclohex-1-enylmethyl)-1,2-dihydrocyclobutabenzene
CAS No.:98115-47-0
Molecular Formula:C₁₈H₁₉NO₂
Molecular Weight:281.354
Hs Code.:

Synonyms:1-cyano-5-methoxy-1-(2-methyl-4-oxocyclohex-1-enylmethyl)-1,2-dihydrocyclobutabenzene

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Chemical Property of 1-cyano-5-methoxy-1-(2-methyl-4-oxocyclohex-1-enylmethyl)-1,2-dihydrocyclobutabenzene

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Technology Process of 1-cyano-5-methoxy-1-(2-methyl-4-oxocyclohex-1-enylmethyl)-1,2-dihydrocyclobutabenzene

There total 1 articles about 1-cyano-5-methoxy-1-(2-methyl-4-oxocyclohex-1-enylmethyl)-1,2-dihydrocyclobutabenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1199-31-1
1-cyano-5-methoxybenzocyclobutane

: 42723-25-1
3-methyl-4-methylenecyclohex-2-enone

: 98115-47-0
1-cyano-5-methoxy-1-(2-methyl-4-oxocyclohex-1-enylmethyl)-1,2-dihydrocyclobutabenzene

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; at -78 ℃; for 1h;

Reference yield:

: 98115-47-0
1-cyano-5-methoxy-1-(2-methyl-4-oxocyclohex-1-enylmethyl)-1,2-dihydrocyclobutabenzene

: 98115-53-8,98243-17-5
C₂₄H₂₈O₂S

Guidance literature:: Multi-step reaction with 6 steps

1: 73 percent / toluene-p-sulphonic acid / benzene / 2 h / Heating

2: 80 percent / liq. NH₃, sodium / ethanol; tetrahydrofuran / 3 h / -78 °C

3: 78 percent / 10percent HCl / methanol / 5 h / Ambient temperature

4: 52 percent / Et₃N / 12 h / Ambient temperature

5: 62 percent / tetrahydrofuran / 1 h / 0 °C

6: 2.) MCPBA / 1.) 1,2-dichlorobenzene, reflux, 5 h.; 2.) methylene dichloride, room temp., 30 min.

With hydrogenchloride; ammonia; sodium; triethylamine; 3-chloro-benzenecarboperoxoic acid; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; ethanol; benzene;

Reference yield:

: 98115-47-0
1-cyano-5-methoxy-1-(2-methyl-4-oxocyclohex-1-enylmethyl)-1,2-dihydrocyclobutabenzene

: 98115-50-5
5-methoxy-1-(2-methyl-4-oxocyclohex-2-enylmethyl)-1,2-dihydrocyclobutabenzene

Guidance literature:: Multi-step reaction with 3 steps

1: 73 percent / toluene-p-sulphonic acid / benzene / 2 h / Heating

2: 80 percent / liq. NH₃, sodium / ethanol; tetrahydrofuran / 3 h / -78 °C

3: 78 percent / 10percent HCl / methanol / 5 h / Ambient temperature

With hydrogenchloride; ammonia; sodium; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; ethanol; benzene;