Cp(*)W(NO)(η(2)-CPhCH2)(Cl)

Base Information

Chemical Name:Cp(*)W(NO)(η(2)-CPhCH2)(Cl)
CAS No.:241144-84-3
Molecular Formula:C₁₈H₂₂ClNOW
Molecular Weight:487.682
Hs Code.:

Synonyms:

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Chemical Property of Cp(*)W(NO)(η(2)-CPhCH2)(Cl)

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Technology Process of Cp(*)W(NO)(η(2)-CPhCH2)(Cl)

There total 1 articles about Cp(*)W(NO)(η(2)-CPhCH2)(Cl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: (η-pentamethylcyclopentadienyl)(nitrosyl)dichlorotungsten

: Mg(CPhCH₂)2*x(dioxane)

: 241144-84-3
Cp(*)W(NO)(η(2)-CPhCH2)(Cl)

Guidance literature:: In tetrahydrofuran; (inert atmosphere); equiv. amt.; solid reagents colling (-100°C),THF addn. (precooled, -35°C), warming (room temp.), stirring (ro om temp., 15 min); evapn. (vac.), washing (Et2O), drying (vac., 5 min), CH2Cl2 addn., filtration (Celite), filtrate concg., hexane addn., crystn. on cooling (-35°C, overnight); 2nd fraction from mother liquor on concg. and cooling; elem. anal.;
DOI:10.1021/om990178y

Reference yield: 87.0%

: 241144-84-3
Cp(*)W(NO)(η(2)-CPhCH2)(Cl)

: 124-02-7
diallylamine

: 241144-92-3
Cp(*)W(NO)(η(2)-CHPhCH2N(C3H5)2)(Cl)

Guidance literature:: In tetrahydrofuran; (inert atmosphere); amine excess; W-compd. dissolved in THF and cooled (-196°C), vacuum-transfer of amine, warming to room temp., stirring (room temp., 15 min); evapn. (vac.), CH2Cl2/hexane (1:2) addn., filtration (Celite), filtrate concg., hexane addn., crystn. on cooling (-35°C, 3 d); elem. anal.;
DOI:10.1021/om990178y

Reference yield: 83.0%

: 241144-84-3
Cp(*)W(NO)(η(2)-CPhCH2)(Cl)

: 532-31-0
silver benzoate

: 241144-86-5
Cp(*)W(NO)(η(1)-CPh=CH2)(η(2)-O2CPh)

Guidance literature:: In dichloromethane; (inert atmosphere); equiv. amt.; mixed at -35°C, warming (room temp.), stirring (room temp., 15 min); evapn. (vac.), washing (Et2O), filtration (Celite), filtrate concg., hexane addn., crystn. on cooling (-35°C, overnight); 2nd fraction from mother liquor on concg. and cooling; elem. anal.;
DOI:10.1021/om990178y