Silver benzoate, AgOBz

Base Information

• Chemical Name: Silver benzoate, AgOBz
• CAS No.: 532-31-0
• Molecular Formula: C7H6AgO2
• Molecular Weight: 228.984
• Hs Code.: 28432900
• NSC Number: 97388,88938
• ChEMBL ID: CHEMBL2001454
• Mol file: 532-31-0.mol

Synonyms:Silver benzoate, AgOBz;Silver benzoate (AgOBz), AgOBz;C7H6O2.Ag;C7-H6-O2.Ag;NSC-88938;NCI60_042175;SCHEMBL27264;CHEMBL2001454;NSC88938;NSC97388;NSC-97388;FT-0696272

Chemical Property of Silver benzoate, AgOBz

Chemical Property:

• Appearance/Colour: Off-White Crystalline Powder
• Vapor Pressure: 0.0122mmHg at 25°C
• Melting Point: 7-8°C(lit.)
• Boiling Point: 249.3 °C at 760 mmHg
• Flash Point: 111.4 °C
• PSA: 26.30000
• Density: 1.103g/mLat 25°C(lit.)
• LogP: 1.30770
• Storage Temp.: Store below +30°C.
• Sensitive.: Light Sensitive
• Solubility.: cold water: soluble385 part(lit.)
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 228.94187
• Heavy Atom Count: 10
• Complexity: 104

Purity/Quality:

97% ^*data from raw suppliers

Silver(I)Benzoate ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=O)O.[Ag]
• Uses: Silver benzoate is an aromatic salt that is used as a catalyst to prepare β-amino acids (such as N-Acetyl-β-alanine) from α-amino acids (such as D-Alanine). Silver benzoate is also used as a catalyst in Wolff rearrangement reactions.

Technology Process of Silver benzoate, AgOBz

There total 8 articles about Silver benzoate, AgOBz which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

silver nitrate + benzoic acid (65-85-0,8013-63-6) → silver benzoate (532-31-0)

Guidance literature:

With NaOH; In water; acetonitrile; to aq. soln. of acid aq. soln. of NaOH added with stirring, then soln. of AgNO3 in CH3CN added under stirring; soln. slowly evapd. in air for 48 h, ppt. filtered, washed (H2O), dried (avc.); elem. anal.;

DOI:10.1081/SIM-200035701

Reference yield: 90.0%

ammonium benzoate (1863-63-4) + silver nitrate → silver benzoate (532-31-0)

Guidance literature:

In water; dropwise addn. of a satd. aq. soln. of AgNO3 to an aq. soln. of ammonium benzoate; pptn., cooling in ice, filtration, washing (cold water, cold ethanol, ether), drying by suction;

Reference yield: 79.0%

benzoic acid (65-85-0,8013-63-6) + silver(l) oxide (20667-12-3) → silver benzoate (532-31-0)

Guidance literature:

In acetonitrile; at 20 ℃; for 24h; Darkness;

DOI:10.1016/j.ica.2018.10.057

upstream raw materials:

benzoic acid

sodium benzoate

ammonium benzoate

silver(l) oxide

Downstream raw materials:

iodoxy benzoic acid

1-phenylethane-1,2-diyl dibenzoate

phenylethane 1,2-diol

propene

Refernces

Reaction of Enol Silyl Ethers with Silver Carboxylate-Iodine. Synthesis of α-Acyloxy Carbonyl Compounds

10.1021/jo00326a023

The research focuses on the synthesis of α-acyloxy carbonyl compounds through the reaction of enol silyl ethers with silver carboxylates and iodine. The purpose of this study is to develop a new and efficient method for introducing oxygen adjacent to a carbonyl group, which is a useful functionalization in organic synthesis. The researchers found that this method allows for a wide range of variation in the acyloxy portion of the molecule and is particularly successful with five- and six-membered ring enol silyl ethers. However, when applied to larger ring sizes, the formation of α-iodo carbonyl compounds occurs as a significant side reaction. The study concludes that the method is regiospecific and mild, making it potentially useful for functionalizing cyclopentanones and cyclohexanones. The chemicals used in the process include various enol silyl ethers, silver carboxylates such as silver acetate, silver benzoate, and silver trifluoroacetate, and iodine.