Technology Process of bis(toluene-3,4-dithiolato)germanium(IV)
There total 1 articles about bis(toluene-3,4-dithiolato)germanium(IV) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
triethylamine;
In
benzene;
byproducts: triethylammonium chloride; under N2, soln. of GeCl4 in benzene added dropwise under stirring to soln. of ligand and Et3N (molar ratio 1:2:4) in benzene at room temp., heated under reflux for 1 h; solvent evapd., treated with water, ppt. filtered under suction, air dried, to suspn. in MeCN at 81°C added Et4NCl in small amt., filtered hot, cooled to room temp.; elem. anal.;
DOI:10.1021/ic50226a019
- Guidance literature:
-
In
acetonitrile;
byproducts: potassium bromide, water; under N2, Ge-complex and KF*2H2O suspd. in soln. of Ph3PMeBr (molar ratio 1:2:1) in MeCN, heated under reflux for 3 h; cooled to room temp., filtered, filtrate concd., cooled to 0°C, recrystd. from MeCN at 0°C; elem. anal.;
DOI:10.1021/ic50226a019
