methyltriphenylphosphonium fluorobis(4-methylbenzene-1,2-dithiolato)germanate

Base Information

• Chemical Name: methyltriphenylphosphonium fluorobis(4-methylbenzene-1,2-dithiolato)germanate
• CAS No.: 79084-39-2
• Molecular Formula: C₁₄H₁₂FGeS₄*C₁₉H₁₈P
• Molecular Weight: 677.427
• Mol file: 79084-39-2.mol

Synonyms:

Chemical Property of methyltriphenylphosphonium fluorobis(4-methylbenzene-1,2-dithiolato)germanate

Chemical Property:

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Useful:

Technology Process of methyltriphenylphosphonium fluorobis(4-methylbenzene-1,2-dithiolato)germanate

There total 1 articles about methyltriphenylphosphonium fluorobis(4-methylbenzene-1,2-dithiolato)germanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium fluoride dihydrate + bis(toluene-3,4-dithiolato)germanium(IV) (79084-23-4) + Methyltriphenylphosphonium bromide (1779-49-3) → methyltriphenylphosphonium fluorobis(4-methylbenzene-1,2-dithiolato)germanate (79084-39-2)

Guidance literature:

In acetonitrile; byproducts: potassium bromide, water; under N2, Ge-complex and KF*2H2O suspd. in soln. of Ph3PMeBr (molar ratio 1:2:1) in MeCN, heated under reflux for 3 h; cooled to room temp., filtered, filtrate concd., cooled to 0°C, recrystd. from MeCN at 0°C; elem. anal.;

DOI:10.1021/ic50226a019

upstream raw materials:

bis(toluene-3,4-dithiolato)germanium(IV)

Methyltriphenylphosphonium bromide