Thiophosphoric acid S-(2,3-bis-octyloxy-propyl) ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl) ester

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Chemical Name:Thiophosphoric acid S-(2,3-bis-octyloxy-propyl) ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl) ester
CAS No.:144944-72-9
Molecular Formula:C₆₀H₈₁O₁₀PS
Molecular Weight:1025.34
Hs Code.:

Synonyms:

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Chemical Property of Thiophosphoric acid S-(2,3-bis-octyloxy-propyl) ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl) ester

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Technology Process of Thiophosphoric acid S-(2,3-bis-octyloxy-propyl) ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl) ester

There total 4 articles about Thiophosphoric acid S-(2,3-bis-octyloxy-propyl) ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 111-85-3
n-chlorooctane

: 144944-72-9
Thiophosphoric acid S-(2,3-bis-octyloxy-propyl) ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl) ester

Guidance literature:: Multi-step reaction with 4 steps

1: 50percent aq.NaOH, tetrabutylammonium bromide / benzene / 72 h / Ambient temperature

2: Na, n-BuOH

3: 1) n-BuLi / 1) THF, 0 deg C, 30 min, 2) r.t., 1 h

4: 1) trimethylsilyl bromide (TMSBr), 2) triisopropylbenzenesulfonyl chloride (TPSCl), NEt₃, pyridine / 1) CH₂Cl₂, r.t., 6 h, 2) r.t., 24 h

With pyridine; sodium hydroxide; n-butyllithium; trimethylsilyl bromide; triisopropylbenzenesulfonyl chloride; tetrabutylammomium bromide; sodium; triethylamine; butan-1-ol; In benzene;
DOI:10.1016/0040-4039(93)88048-N

Reference yield:

: 144944-70-7
2,3-Bis-octyloxy-propane-1-thiol

: 144944-72-9
Thiophosphoric acid S-(2,3-bis-octyloxy-propyl) ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl) ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1) n-BuLi / 1) THF, 0 deg C, 30 min, 2) r.t., 1 h

2: 1) trimethylsilyl bromide (TMSBr), 2) triisopropylbenzenesulfonyl chloride (TPSCl), NEt₃, pyridine / 1) CH₂Cl₂, r.t., 6 h, 2) r.t., 24 h

With pyridine; n-butyllithium; trimethylsilyl bromide; triisopropylbenzenesulfonyl chloride; triethylamine;
DOI:10.1016/0040-4039(93)88048-N

Reference yield:

: 144944-69-4
(2,3-Bis-octyloxy-propylsulfanylmethyl)-benzene

: 144944-72-9
Thiophosphoric acid S-(2,3-bis-octyloxy-propyl) ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl) ester

Guidance literature:: Multi-step reaction with 3 steps

1: Na, n-BuOH

2: 1) n-BuLi / 1) THF, 0 deg C, 30 min, 2) r.t., 1 h

3: 1) trimethylsilyl bromide (TMSBr), 2) triisopropylbenzenesulfonyl chloride (TPSCl), NEt₃, pyridine / 1) CH₂Cl₂, r.t., 6 h, 2) r.t., 24 h

With pyridine; n-butyllithium; trimethylsilyl bromide; triisopropylbenzenesulfonyl chloride; sodium; triethylamine; butan-1-ol;
DOI:10.1016/0040-4039(93)88048-N