111-85-3Relevant articles and documents
PREPARATIVE SYNTHESIS OF PRIMARY AND SECONDARY ALKYL CHLORIDES FROM ALCOHOLS
Volynskii, N. P.,Perepelitchenko, L. I.,Zegel'man, L. A.
, p. 2326 - 2328 (1987)
-
Regen et al.
, p. 1961,1962-1963 (1979)
Rhenium complex as a useful catalyst for acylative cleavage of ethers
Umeda, Rui,Kaiba, Kenta,Tanaka, Toshimasa,Takahashi, Yuuki,Nishimura, Takashi,Nishiyama, Yutaka
, p. 3089 - 3091 (2010)
It was found that a rhenium complex such as ReBr(CO)5 acts as an efficient catalyst for the acylative cleavage of the carbon-oxygen bond of ethers with acyl chloride, giving the corresponding esters in moderate to good yields.
Olivares,Irgolic
, p. 1399,1400 (1972)
Taking compact NMR to monitoring real reactions in large-scale chemical industries—General considerations and learnings from a lab-scale test case
Nestle, Nikolaus,Lim, Zi Jian,B?hringer, Tobias,Abtmeyer, Sarah,Arenz, Sven,Leinweber, Felix C.,Wei?, Thomas,von Harbou, Erik
, p. 1213 - 1221 (2020)
The considerations for use of compact nuclear magnetic resonance in a large-scale industrial environment clearly differ from those in academic and educational settings and even from those in smaller companies. In the first part of this article, these differences will be discussed along with the additional requirements that need to be fulfilled for successful applicability in different use cases. In the second part of the article, outcomes from different research activities aiming to fulfill these requirements will be presented with a focus on an online reaction-monitoring study on a lab-scale nucleophilic chlorination reaction.
Method for synthesizing 1-chloro-n-octane
-
Paragraph 0032-0041, (2020/01/14)
The invention discloses a method for synthesizing 1-chloro-n-octane. The method comprises the following steps: taking n-octanol and a chlorination reagent as raw materials, and reacting for 1-6 hoursin the presence of a formamide catalyst to obtain the product 1-chloro-n-octane. According to the method, n-octyl alcohol and a chlorination reagent are used as initial raw materials, formamide is used as a catalyst, the catalytic efficiency is high, the operation is simple, the reaction conditions are mild, the selectivity and the yield of the product are relatively high, and the method has a wide industrial application prospect.
METHOD FOR PRODUCING REDUCED HALIDE COMPOUND HAVING UNDERGONE REDUCTION OF CARBON-CARBON UNSATURATED BOND
-
Paragraph 0166-0171; 0208-0213, (2019/11/05)
A halide compound having one or more carbon-carbon unsaturated bonds is catalytically reduced with substantially no dehalogenation to produce a reduced halide compound in which at least one of the one or more unsaturated bonds is reduced. Specifically provided is a method for producing a reduced halide compound including steps of: reacting a nickel compound, a zinc compound, and a borohydride compound in a solvent to obtain a reduction catalyst; and subjecting a halide compound having one or more carbon-carbon unsaturated bonds to catalytic reduction in the presence of the reduction catalyst to reduce at least one of the one or more carbon-carbon unsaturated bonds to thereby obtain a reduced halide compound.