[C₅H₅Fe(CO)2((CH₂)5CO)]⁽¹⁺⁾*PF₆^(1-)=[C₅H₅Fe(CO)2((CH₂)5CO)]PF₆

Base Information

• Chemical Name: [C₅H₅Fe(CO)2((CH₂)5CO)]⁽¹⁺⁾*PF₆^(1-)=[C₅H₅Fe(CO)2((CH₂)5CO)]PF₆
• CAS No.: 73854-34-9
• Molecular Formula: C₁₃H₁₅FeO₃*F₆P
• Molecular Weight: 420.071
• Mol file: 73854-34-9.mol

Synonyms:

Chemical Property of [C₅H₅Fe(CO)2((CH₂)5CO)]⁽¹⁺⁾*PF₆^(1-)=[C₅H₅Fe(CO)2((CH₂)5CO)]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [C₅H₅Fe(CO)2((CH₂)5CO)]⁽¹⁺⁾*PF₆^(1-)=[C₅H₅Fe(CO)2((CH₂)5CO)]PF₆

There total 2 articles about [C₅H₅Fe(CO)2((CH₂)5CO)]⁽¹⁺⁾*PF₆^(1-)=[C₅H₅Fe(CO)2((CH₂)5CO)]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

silver(I) hexafluorophosphate (26042-63-7) + di(cyclopentadienideiron dicarbonyl) (38117-54-3) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → [C5H5Fe(CO)2((CH2)5CO)](1+)*PF6(1-)=[C5H5Fe(CO)2((CH2)5CO)]PF6 (73854-34-9)

Guidance literature:

In dichloromethane; byproducts: Ag; (N2); to soln. of Fe complex and cyclohexanone was added AgPF6 at 0°C; to filtered soln. was added ether, formed red ppt. was recrystd. from CH2Cl2/Et2O and dried in vac.; elem. anal.;

DOI:10.1016/S0022-328X(00)81794-5

Reference yield: 63.8%

hexafluorophosphoric acid + cyclopentadienyl iron(II) dicarbonyl dimer (38117-54-3) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → [C5H5Fe(CO)2((CH2)5CO)](1+)*PF6(1-)=[C5H5Fe(CO)2((CH2)5CO)]PF6 (73854-34-9)

Guidance literature:

With p-benzoquinone; In diethyl ether; dichloromethane; under Ar, Cp2Fe2(CO)4, p-benzoquinone and carbonyl compd. in CH2Cl2 treated with HPF6-etherate in ether with stirring at room temp. for 16 h; treated with ether, ppt. dissolved in CH2Cl2, filtered, pptd. with ether, dried in vac.;

DOI:10.1016/S0022-328X(00)81193-6

upstream raw materials:

silver(I) hexafluorophosphate

di(cyclopentadienideiron dicarbonyl)

cyclohexanone

cyclopentadienyl iron(II) dicarbonyl dimer