trans-[PtCl₂(P(NiPr₂)Ph₂)2]

Base Information

• Chemical Name: trans-[PtCl₂(P(NiPr₂)Ph₂)2]
• CAS No.: 525557-89-5
• Molecular Formula: C₃₆H₄₈Cl₂N₂P₂Pt
• Molecular Weight: 836.724
• Mol file: 525557-89-5.mol

Synonyms:

Chemical Property of trans-[PtCl₂(P(NiPr₂)Ph₂)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[PtCl₂(P(NiPr₂)Ph₂)2]

There total 1 articles about trans-[PtCl₂(P(NiPr₂)Ph₂)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + N,N-diisopropyl-1,1-diphenylphosphanamine (22859-57-0) → trans-[PtCl2(P(NiPr2)Ph2)2] (525557-89-5)

Guidance literature:

In dichloromethane; soln. of ligand in CH2Cl2 was added to soln. of Pt-complex in CH2Cl2, stirred for 2 h at room temp. under N2; solvent was removed in vacuo, washed with hexane, recrystd. from CH2Cl2 and hexane; elem. anal.;

DOI:10.1039/b208886j

Reference yield: 10.0%

hydrogenchloride (7647-01-0,15364-23-5) + trans-[PtCl2(P(NiPr2)Ph2)2] (525557-89-5) → cis-dichlorobis(chlorodiphenylphosphine)platinum(II) (61586-84-3,526214-53-9,51321-28-9)

Guidance literature:

In water; Pt-complex in water was treated with aq. HCl;

DOI:10.1039/b208886j

Reference yield:

trans-[PtCl2(P(NiPr2)Ph2)2] (525557-89-5) + allyl alcohol (107-18-6) → cis-[PtCl2(P(OCH2CHCH2)Ph2)2] (525557-90-8)

Guidance literature:

With hydrogenchloride; In further solvent(s); HCl was bubbled through suspn. of Pt-complex in allyl alcohol for 15 min; monitored by NMR;

DOI:10.1039/b208886j

upstream raw materials:

dichloro( 1,5-cyclooctadiene)platinum(ll)

N,N-diisopropyl-1,1-diphenylphosphanamine

Downstream raw materials:

cis-dichlorobis(chlorodiphenylphosphine)platinum(II)

cis-[PtCl₂(P(OCH₂CHCH₂)Ph₂)2]

cis-[PtCl₂(POMePh₂)2]

cis-[PtCl₂(POEtPh₂)2]