mer-OsCl₃(CCHC(o-C₆H₄Cl)2)(PPh₃)2

Base Information

Chemical Name:mer-OsCl₃(CCHC(o-C₆H₄Cl)2)(PPh₃)2
CAS No.:1005213-71-7
Molecular Formula:C₅₁H₃₉Cl₅OsP₂
Molecular Weight:1081.28
Hs Code.:

mer-OsCl<sub>3</sub>(CCHC(o-C<sub>6</sub>H<sub>4</sub>Cl)2)(PPh<sub>3</sub>)2

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Chemical Property of mer-OsCl₃(CCHC(o-C₆H₄Cl)2)(PPh₃)2

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Technology Process of mer-OsCl₃(CCHC(o-C₆H₄Cl)2)(PPh₃)2

There total 1 articles about mer-OsCl₃(CCHC(o-C₆H₄Cl)2)(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.6%

: 56586-93-7,40802-32-2
dichlorotris(triphenylphosphine)osmium(II)

: 857394-05-9
HCCC(OH)(2-ClC₆H₄)2

: 7647-14-5
sodium chloride

: 1005213-71-7,1005349-38-1
mer-OsCl₃(CCHC(o-C₆H₄Cl)2)(PPh₃)2

Guidance literature:: With HPPh₃BF₄; In dichloromethane; (N2); using Schlenk techniques; stirring of mixt. of OsCl2(PPh3)3, HCCC(OH)(o-C6H4Cl)2, HPPh3BF4 and NaCl in CH2Cl2 for 48 h; removal of solvent under vac., extn. with benzene, filtration, removal of solvent of extract under vac., dissolving in CH2Cl2, addn. of Et2O, pptn., filtration, washing with Et2O and hexane, drying under vac.; elem. anal.;
DOI:10.1021/om200685v

Reference yield: 88.0%

: 1005213-71-7,1005349-38-1
[OsCl₃(CCH=C(2-ClC₆H₄)2)(PPh₃)2]

: 1005213-71-7,1005349-38-1
mer-OsCl₃(CCHC(o-C₆H₄Cl)2)(PPh₃)2

: 1005213-73-9
C₉H₅Cl(C₆H₄Cl)Os((C₆H₅)3P)2Cl

: Os((C₆H₅)3P)2Cl₂(C₉H₅C₆H₄Cl)

Guidance literature:: With triphenylphosphine; zinc; In tetrahydrofuran; mixt. Os isomeric complexes was treated with Zn powder in presence of PPh3 in THF at reflux for 25 min; mixt. was evapd., residue was extracted with C6H6, filtered, concd., Et2O was added, filtrate was evapd., dissolved in CH2Cl2, hexane was added,ppt. was filtered off, washed with hexane, Et2O, chromd. (SiO2, eluent- C6H6, CH2Cl2), dried; elem. anal.;
DOI:10.1002/anie.200703289

Reference yield: 88.0%

: 1005213-71-7,1005349-38-1
[OsCl₃(CCH=C(2-ClC₆H₄)2)(PPh₃)2]

: 1005213-71-7,1005349-38-1
mer-OsCl₃(CCHC(o-C₆H₄Cl)2)(PPh₃)2

: 1005213-73-9
C₉H₅Cl(C₆H₄Cl)Os((C₆H₅)3P)2Cl

: Os((C₆H₅)3P)2Cl₂(C₉H₅C₆H₄Cl)

Guidance literature:: With triphenylphosphine; zinc; In tetrahydrofuran; mixt. Os isomeric complexes was treated with Zn powder in presence of PPh3 in THF at reflux for 25 min; mixt. was evapd., residue was extracted with C6H6, filtered, concd., Et2O was added, filtrate was evapd., dissolved in CH2Cl2, hexane was added,ppt. was filtered off, washed with hexane, Et2O, chromd. (SiO2, eluent- C6H6, CH2Cl2), dried; elem. anal.;
DOI:10.1002/anie.200703289