([2,5-Me2-3,4-Ph2(η5-C4CNH2Ph)]Ru(CO)2H)OTf

Base Information

• Chemical Name: ([2,5-Me2-3,4-Ph2(η5-C4CNH2Ph)]Ru(CO)2H)OTf
• CAS No.: 477178-17-9
• Molecular Formula: CHF₃O₃S*C₂₇H₂₃NO₂Ru
• Molecular Weight: 644.633
• Mol file: 477178-17-9.mol

Synonyms:

Chemical Property of ([2,5-Me2-3,4-Ph2(η5-C4CNH2Ph)]Ru(CO)2H)OTf

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ([2,5-Me2-3,4-Ph2(η5-C4CNH2Ph)]Ru(CO)2H)OTf

There total 1 articles about ([2,5-Me2-3,4-Ph2(η5-C4CNH2Ph)]Ru(CO)2H)OTf which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H (477178-15-7) + trifluorormethanesulfonic acid (1493-13-6) → ([2,5-Me2-3,4-Ph2(η5-C4CNH2Ph)]Ru(CO)2H)OTf (477178-17-9)

Guidance literature:

In dichloromethane-d2; a soln. of Ru-contg. compd. (0.035 mmol) in THF in a NMR tube was evapd.to dryness under high vac.; CD2Cl2 was vac. transferred into the tube; triflic acid (0.035 mmol) was added to a soln. via syringe at -78.degree .C; the NMR tube was placed into a precooled NMR probe at -70°C; NMR spectra;

DOI:10.1021/om020507d

Reference yield:

([2,5-Me2-3,4-Ph2(η5-C4CNH2Ph)]Ru(CO)2H)OTf (477178-17-9) → [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2OTf (477178-16-8)

Guidance literature:

In dichloromethane-d2; byproducts: H2; at -25°C, a soln. of Ru-contg. compd. turned cloudy and some solid pptd.; upon being warmed to room temp., the ppt. redissolved and 9-OTfwas observed; (1)H NMR spectra;

DOI:10.1021/om020507d

upstream raw materials:

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H

trifluorormethanesulfonic acid

Downstream raw materials:

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2OTf