[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H

Base Information

• Chemical Name: [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H
• CAS No.: 477178-15-7
• Molecular Formula: C₂₇H₂₃NO₂Ru
• Molecular Weight: 494.555
• Mol file: 477178-15-7.mol

Synonyms:

Chemical Property of [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H

There total 5 articles about [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

([2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)(μ-CO))2 (477246-90-5,477178-12-4) + hydrogen (1333-74-0) → [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H (477178-15-7)

Guidance literature:

In tetrahydrofuran-d8; Irradiation (UV/VIS); a soln. of Ru-contg. compd. (0.014 mmol) in THF-d8 in NMR tube was degassed and placed under 1 atm of H2 (or 1 atm of a 1:1 mixt. of H2 and CO) at -78°C; the tube was irradiated with UV light (254 nm) for 30-40 h at room temp.; NMR spectra;

DOI:10.1021/om020507d

Reference yield:

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2OTf (477178-16-8) + hydrogen (1333-74-0) → [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H (477178-15-7)

Guidance literature:

With diisopropylethylamine; In dichloromethane; byproducts: diisopropylethyleneamine*HOTf; High Pressure; in CH2Cl2 soln. at room temp. upon addn. of 100 atm of H2; IR-spectra;

DOI:10.1021/om020507d

Reference yield:

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl (477178-18-0) + tri-n-butyl-tin hydride (688-73-3) → [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H (477178-15-7)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1039/c6ob02615j

upstream raw materials:

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl

lithium triethylborohydride

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2OTf

hydrogen

Downstream raw materials:

([2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)(μ-CO))2

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2OTf

([2,5-Me2-3,4-Ph2(η5-C4CNH2Ph)]Ru(CO)2H)OTf