[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2OTf

Base Information

• Chemical Name: [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2OTf
• CAS No.: 477178-16-8
• Molecular Formula: C₂₈H₂₂F₃NO₅RuS
• Molecular Weight: 642.618
• Mol file: 477178-16-8.mol

Synonyms:

Chemical Property of [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2OTf

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2OTf

There total 4 articles about [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2OTf which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl (477178-18-0) + silver trifluoromethanesulfonate (2923-28-6) → [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2OTf (477178-16-8)

Guidance literature:

In ⁽²⁾H₈-toluene; by addn. of AgOTf (0.039 mmol) to a soln. of Ru-contg. compd. (0.032 mmol) in toluene-d8; the conversion was quant. after 24 h; NMR studies;

DOI:10.1021/om020507d

Reference yield: 99.0%

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H (477178-15-7) + trifluorormethanesulfonic acid (1493-13-6) → [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2OTf (477178-16-8)

Guidance literature:

In dichloromethane; byproducts: H2; by addn. of triflic acid to a soln. of Ru-contg. compd. in CH2Cl2 at -78°C; warming to room temp.; NMR studies;

DOI:10.1021/om020507d

Reference yield: 77.0%

([2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)(μ-CO))2 (477246-90-5,477178-12-4) + trifluorormethanesulfonic acid (1493-13-6) → [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2OTf (477178-16-8)

Guidance literature:

In dichloromethane; byproducts: H2; triflic acid (0.21 mmol) was added to a soln. of Ru-contg. compd. (0.10 mmol) in CH2Cl2; after 24 h, 3 mL of water was added; at room temp.; the org. layer was evapd. to give an yellow solid; elem. anal.;

DOI:10.1021/om020507d

upstream raw materials:

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H

trifluorormethanesulfonic acid

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl

silver trifluoromethanesulfonate

Downstream raw materials:

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H

([2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)(μ-CO))2