pentafluorophenylchlorocarbene

Base Information

• Chemical Name: pentafluorophenylchlorocarbene
• CAS No.: 54265-10-0
• Molecular Formula: C₇ClF₅
• Molecular Weight: 214.522
• Mol file: 54265-10-0.mol

Synonyms:

Chemical Property of pentafluorophenylchlorocarbene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of pentafluorophenylchlorocarbene

There total 3 articles about pentafluorophenylchlorocarbene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pentafluorobenzamidine hydrochloride (1187927-16-7) → pentafluorophenylchlorocarbene (54265-10-0)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hypochlorite; lithium chloride / water; dimethyl sulfoxide; pentane / 2 h / 20 °C

2: pentane / laser flash photolysis

With sodium hypochlorite; lithium chloride; In water; dimethyl sulfoxide; pentane; 1: Graham oxidation;

DOI:10.1021/jp2039493

Reference yield:

Pentafluorobenzonitrile (773-82-0) → pentafluorophenylchlorocarbene (54265-10-0)

Guidance literature:

Multi-step reaction with 3 steps

1.1: trimethylaluminum; ammonium chloride / toluene / 48 h / 80 °C / Inert atmosphere

1.2: 1 h

2.1: sodium hypochlorite; lithium chloride / water; dimethyl sulfoxide; pentane / 2 h / 20 °C

3.1: pentane / laser flash photolysis

With sodium hypochlorite; trimethylaluminum; ammonium chloride; lithium chloride; In water; dimethyl sulfoxide; toluene; pentane; 1.1: Garigipati's reaction / 2.1: Graham oxidation;

DOI:10.1021/jp2039493

Reference yield:

3-chloro-3-pentafluorophenyldiazirine (1312886-29-5) → pentafluorophenylchlorocarbene (54265-10-0)

Guidance literature:

In pentane; laser flash photolysis;

DOI:10.1021/jp2039493

upstream raw materials:

pentafluorobenzamidine hydrochloride

3-chloro-3-pentafluorophenyldiazirine

Pentafluorobenzonitrile

Downstream raw materials:

C₇ClF₅*C₉H₁₂O₃

C₁₂H₅ClF₅N

C₁₃H₁₂ClF₅

C₁₃H₁₂ClF₅