Benzylzinc(II) bromide

Base Information

Chemical Name:Benzylzinc(II) bromide
CAS No.:62673-31-8
Molecular Formula:C7H7BrZn
Molecular Weight:236.427
Hs Code.:2931900090
European Community (EC) Number:627-093-6

Synonyms:benzylzinc bromide;BnZnBr;benzyl zinc bromide;Benzylzinc(II) bromide;benzyl zinc(II) bromide;benzylzinc (II) bromide;62673-31-8;SCHEMBL291011;OQPRTUBCROVGHA-UHFFFAOYSA-M

Suppliers and Price of Benzylzinc(II) bromide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Benzylzinc bromide solution 0.5 M in THF
50ml
$ 178.00

Rieke Metals
Benzylzincbromide
100mL
$ 404.00

Matrix Scientific
Benzylzincbromide 0.50MinTHF97%
500ml
$ 1830.00

Matrix Scientific
Benzylzincbromide 0.50MinTHF97%
100ml
$ 612.00

Matrix Scientific
Benzylzincbromide 0.50MinTHF97%
50ml
$ 417.00

American Custom Chemicals Corporation
BENZYLZINC BROMIDE 95.00%
1L
$ 8085.00

American Custom Chemicals Corporation
BENZYLZINC BROMIDE 95.00%
500ML
$ 5428.50

American Custom Chemicals Corporation
BENZYLZINC BROMIDE 95.00%
100ML
$ 2737.35

Alfa Aesar
Benzylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
50ml
$ 156.00

Total 10 raw suppliers

Chemical Property of Benzylzinc(II) bromide

Chemical Property:

Flash Point:1 °F
PSA：0.00000
Density:0.978 g/mL at 25oC
LogP:2.84540
Storage Temp.:2-8°C
Sensitive.:Air Sensitive
Water Solubility.:Reacts with water.
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:233.90225
Heavy Atom Count:9
Complexity:46.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

Benzylzinc bromide solution 0.5 M in THF ^*data from reagent suppliers

Safty Information:

Pictogram(s): F,C
Hazard Codes:F,C,Xn
Statements: 11-14-19-34-40-36/37
Safety Statements: 16-26-36/37/39-45-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:[CH2-]C1=CC=CC=C1.[Zn+2].[Br-]
Uses It is applied in cross coupling reactions. Benzylzinc bromide solution can be used as a nucleophile for the Mannich-type synthesis of 1,2-diarylethylpiperazines. It can also undergo C?C cross coupling reactions with aryl halides.

Technology Process of Benzylzinc(II) bromide

There total 6 articles about Benzylzinc(II) bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 100-39-0
benzyl bromide

: 7440-66-6
zinc

: 62673-31-8
benzyl(bromo)zinc

Guidance literature:: zinc; With chloro-trimethyl-silane; ethylene dibromide; In tetrahydrofuran; at 50 ℃; for 0.0166667h; Inert atmosphere; Sealed tube;

benzyl bromide; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere; Sealed tube;
DOI:10.1021/acs.orglett.9b00031