[(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(tert-butylisonitrile)(diethylamine)] hexafluorophosphate

Base Information

• Chemical Name: [(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(tert-butylisonitrile)(diethylamine)] hexafluorophosphate
• CAS No.: 908140-64-7
• Molecular Formula: C₃₂H₄₀N₂PRu*F₆P
• Molecular Weight: 729.691
• Mol file: 908140-64-7.mol

Synonyms:

Chemical Property of [(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(tert-butylisonitrile)(diethylamine)] hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(tert-butylisonitrile)(diethylamine)] hexafluorophosphate

There total 1 articles about [(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(tert-butylisonitrile)(diethylamine)] hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

thallium(I) hexafluorophosphate (60969-19-9) + (η5-cyclopentadienyl)Ru(PPh3)(CN-t-Bu)Cl + diethylamine (109-89-7) → [(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(tert-butylisonitrile)(diethylamine)] hexafluorophosphate (908140-64-7)

Guidance literature:

In dichloromethane; (N2); Schlenk tube charged with soln. of (C5H5)Ru(P(C6H5)3)(CNC(CH3)3)(Cl) in dichloromethane and TlPF6, stirred in the dark at room temp. for 1h, addn. of excess diethylamine, stirred in the dark at room temp. over night; filtration, evapn. of filtrate (reduced pressure), recrystn. from CH2Cl2/Et2O (1:3) at -30 °C;

DOI:10.1016/j.poly.2006.01.016

upstream raw materials:

thallium(I) hexafluorophosphate

diethylamine