[Ir(4'-(C₆H₄CH₃-p)-2,2':6',2''-terpyridine)(CF₃SO₃)3]

Base Information

• Chemical Name: [Ir(4'-(C₆H₄CH₃-p)-2,2':6',2''-terpyridine)(CF₃SO₃)3]
• CAS No.: 414859-78-2
• Molecular Formula: C₂₅H₁₇F₉IrN₃O₉S₃
• Molecular Weight: 962.828
• Mol file: 414859-78-2.mol

Synonyms:

Chemical Property of [Ir(4'-(C₆H₄CH₃-p)-2,2':6',2''-terpyridine)(CF₃SO₃)3]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ir(4'-(C₆H₄CH₃-p)-2,2':6',2''-terpyridine)(CF₃SO₃)3]

There total 1 articles about [Ir(4'-(C₆H₄CH₃-p)-2,2':6',2''-terpyridine)(CF₃SO₃)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

trichloro(4'-(4-tolyl)-2,2':6',2''-terpyridine)iridium(III) (227949-62-4) + trifluorormethanesulfonic acid (1493-13-6) → [Ir(4'-(C6H4CH3-p)-2,2':6',2''-terpyridine)(CF3SO3)3] (414859-78-2)

Guidance literature:

In 1,2-dichloro-benzene; excess of CF3SO3H, reflux for 12 h under N2 and in the dark; solvent and excess of acid were removed with decantation, semi-solid waswashed copious amt. of petroleum ether, dissolved in CH2Cl2, chromy. (a lumina, CH2Cl2), first band was evapd., subsequent recrystn. from acetone-petroleum ether, elem. anal.;

DOI:10.1039/b107163g

Reference yield: 41.0%

ammonium hexafluorophosphate + [Ir(4'-(C6H4CH3-p)-2,2':6',2''-terpyridine)(CF3SO3)3] (414859-78-2) + 4′-(4-amino-phenyl)-2,2′:6′,2′′-terpyridine (178265-65-1) → [Ir(4'-(p-CH3C6H4)-2,2':6',2''-terpyridine)(4'-(p-H2NC6H4)-2,2':6',2''-terpyridine)](PF6)3

Guidance literature:

In water; ethylene glycol; under N2, dark, 1 equiv. of amine, heating (160 °C, 20 min, (CH2OH)2), satd. aq. NH4PF6 soln. was added, washing with cold H2O and MeOH-Et2O, drying in vac., chromy. (silica, from MeCN to MeCN:H2O-aq.KNO3=70:27.5:2.5), metathesis into PF6-compd.; recrystn. from acetone-Et2O, elem. anal.;

DOI:10.1039/b107163g

upstream raw materials:

trichloro(4'-(4-tolyl)-2,2':6',2''-terpyridine)iridium(III)

trifluorormethanesulfonic acid