triphenyl[3-(4'-cyano-4-biphenyloxy)propyl]tin

Base Information

• Chemical Name: triphenyl[3-(4'-cyano-4-biphenyloxy)propyl]tin
• CAS No.: 648930-64-7
• Molecular Formula: C₃₄H₂₉NOSn
• Molecular Weight: 586.32
• Mol file: 648930-64-7.mol

Synonyms:

Chemical Property of triphenyl[3-(4'-cyano-4-biphenyloxy)propyl]tin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triphenyl[3-(4'-cyano-4-biphenyloxy)propyl]tin

There total 1 articles about triphenyl[3-(4'-cyano-4-biphenyloxy)propyl]tin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

triphenylstannane (892-20-6) + 4’-(allyloxy)-[1,1'-biphenyl]-4-carbonitrile (111928-38-2) → triphenyl[3-(4'-cyano-4-biphenyloxy)propyl]tin (648930-64-7)

Guidance literature:

With 2,2'-azobisisobutyronitrile; In melt; (N2); heating a melt of tin compd. with ligand and AIBN to 140°C for 1 h; cooling, column chromy. (SiO2, gradient petroleum ether/CH2Cl2); elem. anal.;

DOI:10.1016/j.jorganchem.2003.08.003

Reference yield: 65.0%

triphenyl[3-(4'-cyano-4-biphenyloxy)propyl]tin (648930-64-7) + bromine (7726-95-6) → phenyl[3-(4'-cyano-4-biphenyloxy)propyl]tin dibromide

Guidance literature:

In dichloromethane; dropwise addn. of a soln. of Br2 in CH2Cl2 to a soln. of tin compd. in CH2Cl2 at 0°C, stirring for 24 h; evapn., recrystn. (petroleum ether/CH2Cl2 1:1); elem. anal.;

DOI:10.1016/j.jorganchem.2003.08.003

upstream raw materials:

triphenylstannane

4’-(allyloxy)-[1,1'-biphenyl]-4-carbonitrile