RuBr₂(P(C₆H₅)3)3

Base Information

• Chemical Name: RuBr₂(P(C₆H₅)3)3
• CAS No.: 56586-92-6
• Molecular Formula: C₅₄H₄₅Br₂P₃Ru
• Molecular Weight: 1047.75
• Mol file: 56586-92-6.mol

Synonyms:

Chemical Property of RuBr₂(P(C₆H₅)3)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RuBr₂(P(C₆H₅)3)3

There total 2 articles about RuBr₂(P(C₆H₅)3)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

ruthenium(III) chloride trihydrate (14898-67-0) + lithium bromide monohydrate + triphenylphosphine (603-35-0) → {RuBr2(triphenylphosphine)3} (56586-92-6,15709-75-8)

Guidance literature:

In methanol; to MeOH soln. of RuCl3*3H2O was added LiBr*H2O, refluxed for 24 h, PPh3 was added, refluxed for 5 h under N2; collected, washed with MeOH;

DOI:10.1021/ic000392a

Reference yield:

ruthenium(III) chloride trihydrate (14898-67-0) + triphenylphosphine (603-35-0) + lithium bromide (7550-35-8) → {RuBr2(triphenylphosphine)3} (56586-92-6,15709-75-8)

Guidance literature:

In methanol; shaking with large excess LiBr;;

DOI:10.1016/0022-1902(66)80191-4

Reference yield: 91.0%

{RuBr2(triphenylphosphine)3} (56586-92-6,15709-75-8) + trifluorormethanesulfonic acid (1493-13-6) + Dimethyl(phenyl)phosphine (672-66-2) → tri-μ-bromobis[tris(dimethylphenylphosphine)ruthenium(II)] triflate

Guidance literature:

In methanol; ethanol; dichloromethane; (N2); refluxing the Ru complex and ligand in EtOH for 4 h, solvent removal (vac.), stirring with benzene/Et2O, washing (Et2O), dissoln. (CH2Cl2), refluxing with CF3SO3H in MeOH for 16 h; evapn. (vac.), recrystn. (CH2Cl2/Et2O); elem. anal.;

DOI:10.1039/a705675c

upstream raw materials:

ruthenium(III) chloride trihydrate

triphenylphosphine

lithium bromide

Downstream raw materials:

[N-benzyl(salicylideneimine(N,O)),N-benzyl(salicylideneimine(C,N,O))]-(triphenylphosphine)ruthenium(III)

bis-[N-benzyl(salicylideneimine)]bis-(triphenylphosphine)ruthenium(II)

{RuBr₂(1,3-di-p-tolyltriazenido)(PPh₃)2}

{RuBr₂(1,3-di-p-chlorphenyltriazenido)(PPh₃)2}