WH₆(PPh(i-Pr)2)3

Base Information

Chemical Name:WH₆(PPh(i-Pr)2)3
CAS No.:75516-74-4
Molecular Formula:C₃₆H₆₃P₃W
Molecular Weight:772.668
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of WH₆(PPh(i-Pr)2)3

Chemical Property:

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Technology Process of WH₆(PPh(i-Pr)2)3

There total 2 articles about WH₆(PPh(i-Pr)2)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

: 36133-73-0
hexamethyltungsten(VI)

: 6372-43-6
diisopropylphenylphosphane

: 75516-74-4
WH₆(PPh(i-Pr)2)3

Guidance literature:: With hydrogen; In hexane; High Pressure; ligand was added to soln. of W-compd. (molar ratio 1:3.4) in hexane, subjected to H2 at 300 atm for 5 d; according to Gregson, D.; Howard, J. A. K.; Nicholls, J. N.; Spencer, J. L.; Turner, D. G. J. Chem. Soc., Chem. Commun. 1980, 572-573; filtered, evapd. at reduced pressure, dried under vac. for 24 h, recrystd. from hexane at -20°C; elem. anal.;

Reference yield:

: tetrakis(η(3)-allyl)tungsten;

: 1333-74-0
hydrogen

: 6372-43-6
diisopropylphenylphosphane

: 75516-74-4
WH₆(PPh(i-Pr)2)3

Guidance literature:: In benzene-d6; absence of air and moisture; closed H2-filled tube, 80°C (NMR monitoring, periodical replenishing with H2); not isolated, detd. by NMR spectroscopy;
DOI:10.1016/0022-328X(95)05500-O