Au(C₆F₅)(C₆F₃H₂)2(C₄H₈S)

Base Information

• Chemical Name: Au(C₆F₅)(C₆F₃H₂)2(C₄H₈S)
• CAS No.: 75563-78-9
• Molecular Formula: C₂₂H₁₂AuF₁₁S
• Molecular Weight: 714.352
• Mol file: 75563-78-9.mol

Synonyms:

Chemical Property of Au(C₆F₅)(C₆F₃H₂)2(C₄H₈S)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Au(C₆F₅)(C₆F₃H₂)2(C₄H₈S)

There total 1 articles about Au(C₆F₅)(C₆F₃H₂)2(C₄H₈S) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

pentafluorophenyl(tetrahydrothiophene)gold(I) + thallium(III)(24)Cl(6-C6F3H2)2 (74625-70-0) → Au(C6F5)(C6F3H2)2(C4H8S) (75563-78-9)

Guidance literature:

In benzene; stirred for 3 h at room temp., refluxed for 2 h; evapd., recrystd. (ether/hexane); elem. anal.;

DOI:10.1016/S0022-328X(00)96182-5

Reference yield: 83.0%

[Au(C6F5)(C6H2F3)2(C4H8S)] (75563-78-9) + tetrabutylammomium bromide (1643-19-2) → [N(C4H9)4](1+)*[Au(C6F5)(C6H2F3)2Br](1-)=[N(C4H9)4][Au(C6F5)(C6H2F3)2Br] (84477-55-4)

Guidance literature:

In dichloromethane; mixt. of Au complex and NBu4Br in CH2Cl2 stirred for 1 h at 25°C; concd., hexane added, ppt. recrystd. from CH2Cl2-hexane; elem. anal.;

DOI:10.1039/DT9820001971

Reference yield:

[Au(C6F5)(C6H2F3)2(C4H8S)] (75563-78-9) + tetrabutylammomium bromide (1643-19-2) → [N(C4H9)4](1+)*[Au(C6F5)2(C6H2F3)2](1-)=[N(C4H9)4][Au(C6F5)2(C6H2F3)2] (131614-59-0)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane

2: diethyl ether

In diethyl ether; dichloromethane;

DOI:10.1039/DT9820001971

upstream raw materials:

thallium(III)⁽²⁴⁾Cl(6-C₆F₃H₂)2

Downstream raw materials:

[N(C₄H₉)4]⁽¹⁺⁾*[Au(C₆F₅)(C₆H₂F₃)2Br]^(1-)=[N(C₄H₉)4][Au(C₆F₅)(C₆H₂F₃)2Br]

[N(C₄H₉)4]⁽¹⁺⁾*[Au(C₆F₅)2(C₆H₂F₃)2]^(1-)=[N(C₄H₉)4][Au(C₆F₅)2(C₆H₂F₃)2]

Refernces