74625-70-0

Upstream product

• 13453-32-2 thallium (III) chloride 
• 53732-49-3 lithium-2,4,6-trifluorophenyl 
• 121772-59-6 silver-2,4,6-trifluorophenyl 

Downstream Products

• 75563-78-9 Au(C₆F₅)(C₆F₃H₂)2(C₄H₈S) 
• 75563-76-7 Au(C₆F₃H₂)2ClP(C₆H₅)3 
• 131747-06-3 Au(2,4,6-C₆F₃H₂)3 
• 74559-21-0 Bu₄N[Au(2,4,6-C₆F₃H₂)3Cl] 

Relevant academic research and scientific papers

Reactions of thallium(III) chloride with (aryl)silver(I) complexes. Crystal structure of (mes=mesityl)

The arylsilver derivatives AgR (R=mesityl, C6F3H2, C6F5) react with TlCl3 to give arylthallium(III) complexes of the types , TlClR2 or TlR3.The structure of has been established by X-ray crystallography; it consists of

CHLOROBIS(POLYFLUOROPHENYL)THALLIUM(III) COMPLEXES AND THEIR REACTIONS WITH GOLD(I) AND TIN(II) COMPOUNDS

The reaction of TlCl3 with RLi leads to complexes of the general formula TlR2Cl (R=C6F5, p-C6F4H, m-C6F4H, 2,4,6-C6F3H2, p-C6FH4 or m-CF3C6H4).Some of these undergo oxidative addition reactions with gold(I) complexes to give polyfluorophenyl derivatives of the types AuR2ClL and Au(C6F5)R2(tht) (tht=tetrahydrothiophen), and with SnCl2 to give oily materials from which stable solids of the general formula Q can be isolated by addition of QCl (Q=Et4N or Ph3BzP).