Rh(2-(4-tert-butyl-phenyl)-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene)((S)-2,2'-bis(diphenylphosphino)-1,1'-biphenyl)SbF₆

Base Information

• Chemical Name: Rh(2-(4-tert-butyl-phenyl)-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene)((S)-2,2'-bis(diphenylphosphino)-1,1'-biphenyl)SbF₆
• CAS No.: 888478-34-0
• Molecular Formula: C₅₇H₅₆OP₂Rh*F₆Sb
• Molecular Weight: 1157.66
• Mol file: 888478-34-0.mol

Synonyms:

Chemical Property of Rh(2-(4-tert-butyl-phenyl)-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene)((S)-2,2'-bis(diphenylphosphino)-1,1'-biphenyl)SbF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Rh(2-(4-tert-butyl-phenyl)-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene)((S)-2,2'-bis(diphenylphosphino)-1,1'-biphenyl)SbF₆

There total 1 articles about Rh(2-(4-tert-butyl-phenyl)-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene)((S)-2,2'-bis(diphenylphosphino)-1,1'-biphenyl)SbF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

silver hexafluoroantimonate (26042-64-8) + [RhCl(2-(4-tert-butyl-phenyl)-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene)]2 (888478-32-8,913744-88-4) + 2,2'-bis(diphenylphosphino)biphenyl (84783-64-2) → Rh(2-(4-tert-butyl-phenyl)-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene)((S)-2,2'-bis(diphenylphosphino)-1,1'-biphenyl)SbF6 (888478-34-0)

Guidance literature:

In tetrahydrofuran; (N2); std. Schlenk technique; THF was added to mixt. of Rh complex and AgSbF6; stirred at room temp. for 0.5 h; soln. of ligand in THF was addeddropwise; mixt. was stirred at room temp. for 0.5 h; filtered through Celite; concd.; triturated with Et2O; filtered; dissolved in EtOH; slowly evapd. under Ar; elem. anal.;

DOI:10.1016/j.jorganchem.2005.09.050

Reference yield: 95.0%

Rh(2-(4-tert-butyl-phenyl)-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene)((S)-2,2'-bis(diphenylphosphino)-1,1'-biphenyl)SbF6 (888478-34-0) + carbon monoxide (201230-82-2) → [Rh(CO)2((S)-2,2'-bis(diphenylphosphino)-1,1'-biphenyl)]SbF6 (888478-36-2)

Guidance literature:

In chloroform; byproducts: MeC(CH2C(Me)OMe)CHCHCHCHCC6H4-t-Bu; (N2); std. Schlenk technique; CO was passed through soln. of Rh complex in CHCl3 for 5 min; solvent removed (vac.); triturated with Et2O; filtered; dried (vac.); elem. anal.;

DOI:10.1016/j.jorganchem.2005.09.050

upstream raw materials:

silver hexafluoroantimonate

[RhCl(2-(4-tert-butyl-phenyl)-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene)]2

2,2'-bis(diphenylphosphino)biphenyl

Downstream raw materials:

[Rh(CO)2((S)-2,2'-bis(diphenylphosphino)-1,1'-biphenyl)]SbF₆