[K(2,2,2-cryptand)][trans-IrH₄(P(C₆H₁₁)3)2]

Base Information

Chemical Name:[K(2,2,2-cryptand)][trans-IrH₄(P(C₆H₁₁)3)2]
CAS No.:439095-61-1
Molecular Formula:C₁₈H₃₆N₂O₆*C₃₆H₇₀IrP₂*K
Molecular Weight:1172.71
Hs Code.:

[K(2,2,2-cryptand)][trans-IrH<sub>4</sub>(P(C<sub>6</sub>H<sub>11</sub>)3)2]

Synonyms:

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Chemical Property of [K(2,2,2-cryptand)][trans-IrH₄(P(C₆H₁₁)3)2]

Chemical Property:

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Technology Process of [K(2,2,2-cryptand)][trans-IrH₄(P(C₆H₁₁)3)2]

There total 2 articles about [K(2,2,2-cryptand)][trans-IrH₄(P(C₆H₁₁)3)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: 65231-12-1
pentahydridobis(tricyclohexylphosphine)iridium(III)

: potassium hydride

: 23978-09-8
[2.2.2]cryptande

: 439095-61-1
[K(2,2,2-cryptand)][trans-IrH₄(P(C₆H₁₁)3)2]

Guidance literature:: In tetrahydrofuran; byproducts: H2; under N2, standard Schlenk techniques; Ir complex, KH, 2,2,2-cryptand (molar ratio 1:5:1) and THF combined; stirred for 3 h; filtered; hexanes added slowly with stirring to filtrate; filtered; ppt.washed with hexanes; dried under vac.;
DOI:10.1021/ic0255149

Reference yield:

: 65231-12-1
pentahydridobis(tricyclohexylphosphine)iridium(III)

: 1333-74-0
hydrogen

: potassium hydride

: 23978-09-8
[2.2.2]cryptande

: 439095-61-1
[K(2,2,2-cryptand)][trans-IrH₄(P(C₆H₁₁)3)2]

: [K(2,2,2-cryptand)][IrH₆(PCy₃)]

Guidance literature:: In tetrahydrofuran; byproducts: P(C6H11)3; under H2, standard Schlenk techniques; Ir complex, KH and 2,2,2-cryptandreacted in THF; the title compd. contaminated with K(2,2,2-cryptand)(IrH6(PCy3));
DOI:10.1021/ic0255149

Reference yield:

: 439095-61-1
[K(2,2,2-cryptand)][trans-IrH₄(P(C₆H₁₁)3)2]

: 53470-70-5
IrH₅(P-(i-Pr)3)2

: 439291-48-2
[K(cryptand-2,2,2)][trans-IrH₄(P(i-Pr)3)2]

: 65231-12-1
pentahydridobis(tricyclohexylphosphine)iridium(III)

Guidance literature:: In tetrahydrofuran-d8; under N2, standard Schlenk techniques; in sealed NMR tube; IrH5(P(i-Pr)3)2 and Ir-PCy3 complex (molar ratio 1:1) reacted in THF-d8 at room temp.for 3 and 24 h; equil. react.; not isolated; detd. by (31)P NMR spectra;
DOI:10.1021/ic0255149