N-Benzoyl-2,6-dimethyl-1-azoniabenzene-1-amineanion

Base Information

• Chemical Name: N-Benzoyl-2,6-dimethyl-1-azoniabenzene-1-amineanion
• CAS No.: 17408-43-4
• Molecular Formula: C₁₄H₁₄N₂O
• Molecular Weight: 226.278
• Mol file: 17408-43-4.mol

Synonyms:

Chemical Property of N-Benzoyl-2,6-dimethyl-1-azoniabenzene-1-amineanion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-Benzoyl-2,6-dimethyl-1-azoniabenzene-1-amineanion

There total 3 articles about N-Benzoyl-2,6-dimethyl-1-azoniabenzene-1-amineanion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,6-dimethylpyridine (108-48-5) + benzoyl chloride (98-88-4) → (benzoyl)(2,6-dimethylpyridin-1-ium-1-yl)amide (17408-43-4)

Guidance literature:

2,6-dimethylpyridine; With hydroxylamine-O-sulfonic acid; In tetrahydrofuran; for 0.5h;

benzoyl chloride; With sodium hydroxide; In tetrahydrofuran; at 20 ℃; for 20h;

DOI:10.1021/ja0348647

Reference yield:

benzoyl chloride (98-88-4) + N-amino-2,6-dimethylpyridinium 2,4-dinitrophenolate → (benzoyl)(2,6-dimethylpyridin-1-ium-1-yl)amide (17408-43-4)

Guidance literature:

With sodium hydroxide; In tetrahydrofuran; water; at 20 ℃; for 4h;

DOI:10.1021/jo034456l

Reference yield:

2,6-dimethylpyridine (108-48-5) → (benzoyl)(2,6-dimethylpyridin-1-ium-1-yl)amide (17408-43-4)

Guidance literature:

Multi-step reaction with 2 steps

1: water; tetrahydrofuran / 12 h / 40 °C

2: sodium hydroxide / water; tetrahydrofuran / 4 h / 20 °C

With sodium hydroxide; In tetrahydrofuran; water;

DOI:10.1039/c3cc45410j

upstream raw materials:

2,6-dimethylpyridine

benzoyl chloride

Refernces

• 1、 Legault, Claude,Charette, Andre B.. "Complexation promoted additions to N-benzoyliminopyridinium ylides. A novel and highly regioselective approach to polysubstituted piperidines". . p. 6360 - 6361. Retrieved 2007/10/03.